The incorporation of nanomaterials in the polymer matrix is considered to be a highly effective technique to improve the mechanical properties of resins. In this paper the effects of the addition of different nanoparticles such as single-walled CNT (SWCNT), double-walled CNT (DWCNT), multi-walled CNT (MWCNT), graphene, nanoclay and nanosilica on fracture toughness, strength and stiffness of the epoxy matrix have been reviewed. The Young's modulus (E), ultimate tensile strength (UTS), mode I (GIC) and mode II (GIIC) fracture toughness of the various nanocomposites at different nanoparticle loadings are compared. The review shows that, depending on the type of nanoparticles, the integration of the nanoparticles has a substantial effect on mode I and mode II fracture toughness, strength and stiffness. The critical factors such as maintaining a homogeneous dispersion and good adhesion between the matrix and the nanoparticles are highlighted. The effect of surface functionalization, its relevancy and toughening mechanism are also scrutinized and discussed. A large variety of data comprised of the mechanical properties of nanomaterial toughened composites reported to date has thus been compiled to facilitate the evolution of this emerging field, and the results are presented in maps showing the effect of nanoparticle loading on mode I fracture toughness, stiffness and strength.

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This study presents the response of fiber reinforced composite material composed of woven Kevlar fabric impregnated with a colloidal shear thickening fluid (STF) under high velocity impact loading. The STF was made by dispersing silica nanoparticles at 15, 25, 35 and 45 wt.% loading in polyethylene glycol. The effects of silica nanoparticle loading on energy absorption and ballistic limit were studied experimentally. Rheological results revealed that shear thickening occurred at all four nanosilica loading and higher loading showing the higher shear thickening at lower shear rate. SEM images confirmed good dispersion of nanosilica particles in the suspension. The results of the pull out test show that by increasing nanosilica loading, the force required to pull the yarn out from the fabric impregnated by STF increases. Impact resistance performance of Kevlar fabric is significantly enhanced due to the presence of STF. Although high velocity impact results show that by increasing nanosilica loading, the energy absorption of composites increases, but in high loading of nanosilica, the effectiveness of STF decreases. For further investigation, the energy absorption at the ballistic limit was normalized by the areal density of the neat and impregnated fabrics to give the specific energy absorption (SEA). It is found that the SEA of 15 wt.% nanosilica loading is lower compared to the neat fabric. Also the highest SEA turn out in the case of 35 wt.% STF/Kevlar composites in which the SEA is 2.3 times larger than those of the neat fabric.

Centralized waste plastic recycling is economically challenging, yet distributed recycling and additive manufacturing (DRAM) offers a path that provides consumers with direct economic incentives to recycle. This study explores the technical pathways for DRAM of complex polymer composites using a case study of windshield wiper blades, which are a thermopolymer composite made up of a soft (flexible) and hard material. The distributed manufacturing methods ran from mechanical grinding to fused granular fabrication, heated syringe printing, 3-D printed molds coupled to injection molding and filament production in a recyclebot to fused filament fabrication. The particle size, angle of repose, thermal and rheological properties are characterized for the two sub-materials to define the conditions for the extrusion. A successful pathway was found and the mechanical properties of the resultant components were quantified.Finally, the means to convert scrap windshield wiper blades into useful, high-value, bespoke biomedical products of fingertip grips for hand prosthetic was demonstrated. This study showed that the DRAM model of materials recycling can be used to improve the variety of solutions for a circular economy.

Wind blades are the most expensive parts of wind turbines made from fibre-reinforced polymer composites. The blades play a critical role on the energy production, but they are prone to damage like any other composite components. Leading edge (LE) erosion of the wind turbine blades is one of the common damages, causing a reduction in the annual energy production especially in offshore wind turbine farms. This erosion can be caused by rain, sand and flying solid particles. Coating the blade against erosion using appropriate materials can drastically reduce these losses and hence is of great interest. The sol–gel technique is a convenient method to manufacture thin film coatings, which can protect the blades against the rain erosion, while having negligible effect on the weight of the blades. This article provides an extensive review of the liquid erosion mechanism, water erosion testing procedures and the contributing factors to the erosion of the LE of wind turbine blades. Techniques for improving the erosion resistance of the LE using carbon nanotubes and graphene nano-additives are also discussed.

In this study, the effects of adding nanofillers to an epoxy resin (EP) used as a matrix in glass fibre-reinforced plastic (GFRP) composites have been investigated. Both 1D and 2D nanofillers were used, specifically (1) carbon nanotubes (CNTs), (2) few-layer graphene nanoplatelets (GNPs), as well as hybrid combinations of (3) CNTs and boron nitride nanosheets, and (4) GNPs and boron nitride nanotubes (BNNTs). Tensile tests have shown improvements in the transverse stiffness normal to the fibre direction of up to about 25% for the GFRPs using the 'EP ? CNT' and the 'EP ? BNNT ? GNP' matrices, compared to the composites with the unmodified epoxy ('EP'). Mode I and mode II fracture toughness tests were conducted using double cantilever beam (DCB) and end-notched flexure (ENF) tests, respectively. In the quasi-static mode I tests, the values of the initiation interlaminar fracture toughness, G C IC , of the GFRP composites showed that the transfer of matrix toughness to the corresponding GFRP composite is greatest for the GFRP composite with the GNPs in the matrix. Here, a coefficient of toughness transfer (CTT), defined as the ratio of mode I initiation interlaminar toughness for the composite to the bulk polymer matrix toughness, of 0.68 was recorded. The highest absolute values of the mode I interlaminar fracture toughness at crack initiation were achieved for the GFRP composites with the epoxy matrix modified with the hybrid combinations of nanofillers. The highest value of the CTT during steady-state crack propagation was * 2 for all the different types of GFRPs. Fractographic analysis of the composite surfaces from the DCB and ENF specimens showed that failure was by a combination of cohesive (through the matrix) and interfacial (along the fibre/matrix interface) modes, depending on the type of nanofillers used.

Diffusive flux models, generally used to describe migration in slurry flow applications are shown to be inadequate for vibrated slurry applications, as in these models the diffusion is linked to a mean shearing flow. As a result they cannot describe a vibrated slurry in the steady state (the zero-motion problem). The granular temperature model by McTigue and Jenkins is able to describe this problem and is therefore suitable for oscillated slurries. The parameters that are required to operate the model are derived from a cell model. Previously they had been set to unity, in the absence of any other clue as to what they might be. In the cell model, developed in this paper, which employs the mean field approximation, the parameters are also found to be of the order of magnitude of unity, but especially the parameter that is associated with dissipation is rather larger than unity. It is shown that this larger parameter leads to a more localized effect in oscillated slurry applications than with the previous estimates. The cell model is verified against viscosity measurements and found to be in good agreement when the number of nearest neighbours is set to six.

Auxetic materials or materials with a negative Poisson's ratio have a great potential to be used in many industries because of their specific mechanical properties such as high stiffness and strength with significant weight saving. In this article, the effect of various parameters of the fabrication process on the microstructure