Porous titanium dioxide (TiO 2) films are essential components of dye sensitized solar cells (DSSCs) as well as perovskite solar cells (PSCs). Unfortunately, porosity, refractive index, and scattering properties of these films are only roughly known. This induces uncertainties in modelling and understanding of these solar cells. Since the literature provides only descriptions of the optical properties of the porous TiO 2 layers with unclear relevance to these solar cells, we investigate porous TiO 2 films really used in DSSCs and potentially usable in PSCs. The effective refractive index and the film porosity for different nanostructures that were fabricated from solution-based techniques were determined. The found values are 1.7982 ± 0.005 for the effective refractive index of one kind of TiO 2 films and 1.62 ± 0.002 for another one. These values lead to porosities of 53.5% and 65%, respectively. The scattering of the films can be described by a wavelength-independent effective scattering parameter for one film type and by effective scattering particles with a diameter of 46.5 nm for the other film type. The determined porosities are also of relevance for the ionic transport which is functionally crucial in DSSCs and a disturbance in PSCs.
This paper presses a smart charging decision-making criterion that significantly contributes in enhancing the scheduling of the electric vehicles (EVs) during the charging process.The proposed criterion aims to optimize the charging time, select the charging methodology either DC constant current constant voltage (DC-CCCV) or DC multi-stage constant currents (DC-MSCC), maximize the charging capacity as well as minimize the queuing delay per EV, especially during peak hours. The decision-making algorithms have been developed by utilizing metaheuristic algorithms including the Genetic Algorithm (GA) and Water Cycle Optimization Algorithm (WCOA). The utility of the proposed models has been investigated while considering the Mixed Integer Linear Programming (MILP) as a benchmark. Furthermore, the proposed models are seeded using the Monte Carlo simulation technique by estimating the EVs arriving density to the EVS across the day. WCOA has shown an overall reduction of 13% and 8.5% in the total charging time while referring to MILP and GA respectively.
The thermoelectric effect encompasses three different effects, i.e. Seebeck effect, Peltier effect, and Thomson effect, which are considered as thermally activated materials that alter directions in smart materials. It is currently considered one of the most challenging green energy harvesting mechanisms among researchers. The ability to utilize waste thermal energy that is generated by different applications promotes the use of thermoelectric harvesters across a wide range of applications. This review illustrates the different attempts to fabricate efficient, robust and sustainable thermoelectric harvesters, considering the material selection, characterization, device fabrication and potential applications. Thermoelectric harvesters with a wide range of output power generated reaching the milliwatt range have been considered in this work, with a special focus on the main advantages and disadvantages in these devices. Additionally, this review presents various studies reported in the literature on the design and fabrication of thermoelectric harvesters and highlights their potential applications. In order to increase the efficiency of equipment and processes, the generation of thermoelectricity via thermoelectric materials is achieved through the harvesting of residual energy. The review discusses the main challenges in the fabrication process associated with thermoelectric harvester implementation, as well as the considerable advantages of the proposed devices. The use of thermoelectric harvesters in a wide range of applications where waste thermal energy is used and the impact of the thermoelectric harvesters is also highlighted in this review.
A novel structure for thin-film solar cells is simulated with the purpose of maximizing the absorption of light in the active layer and of reducing the parasitic absorption in other layers. In the proposed structure, the active layer is formed from an amorphous silicon thin film sandwiched between silicon nanowires from above and photonic crystal structures from below. The upper electrical contact consists of an indium tin oxide layer, which serves also as an antireflection coating. A metal backreflector works additionally as the other contact. The simulation was done using a new reliable, efficient and generic optoelectronic approach. The suggested multiscale simulation model integrates the finite-difference time-domain algorithm used in solving Maxwell's equation in three dimensions with a commercial simulation platform based on the finite element method for carrier transport modeling. The absorption profile, the external quantum efficient, and the power conversion efficiency of the suggested solar cell are calculated. A noticeable enhancement is found in all the characteristics of the novel structure with an estimated 32% increase in the total conversion efficiency over a cell without any light trapping mechanisms.
Unique light-trapping structures that improve the efficiency of thin-film solar cells require advanced computational methods that can simulate the propagation of light through the thickness of each material in the solar cell. The simulations community that uses the Lorentz-Drude (LD) model cannot precisely simulate the propagation of light through the entire spectrum of the Sun, due to the difficulty in extrapolating the coefficients of each solar cell material. In this paper, a new technique for modeling dispersive and absorptive material over the Sun's entire wavelength range (200-1700 nm) using the LD model is suggested. The new numerical models are used for simulating light propagation through various one-dimensional light-trapping structures, including metal backreflectors and distributed Bragg reflectors. All the numerical simulation results show agreement with previously published theoretical and experimental results. The proposed simulation technique will help the simulations community in using the LD model to simulate the propagation of light in solar cells more accurately.
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