This study aims to clarify the distribution of groundwater qualitative characteristics in Daqouq district within Kirkuk governorate, the study included 14 wells that were selected in the area located in the southern part of Kirkuk province, and which included different activities such as agricultural, industrial and residential to the north in the Daqouq district. Water samples were collected from the wells once every two months from December 2016 to April 2017. The physical tests were performed such as electrical conductivity, total dissolved solids and chemical tests that included pH, cations such as calcium and magnesium, anions such as sulphates, nitrates and chlorides and concentrations of trace elements such as lead, cadmium and zinc were measured using standard methods. The three- dimension contour maps were drawn to illustrate the distribution of the above properties in the study area. The wells showed that the highest rate of electrical conductivity was 1600 μs/cm in W4 and the highest concentration of calcium in W5 was 260 mg/L and the highest rate of lead was 2.2 μg/L in W13, and they showed that the difference in the quality of water was according to land use, agricultural, residential or industrial, in the properties of electrical conductivity, total dissolved solids, nitrates, chlorides, and trace elements.
The study area is located in Baiji province characterized by anthropogenic activities which may affect the groundwater quality. Therefore, the present work was intended for assessing groundwater quality and its suitability for drinking. Groundwater samples were collected from 33 different well, then analyzed to determine 20 parameter which are TDS, Ca, Mg, Na, K, Cl, SO4, NO3, Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn, As, B and Se. Nemerow Pollution Index Synthetic Pollution Index, and Pollution Index of Groundwater were used for determining groundwater suitability for human consumption. Nemerow Pollution Index values indicate that groundwater pollution is ranged from seriously to moderately polluted. According to Synthetic Pollution Index results, the water samples were moderately polluted to unsuitable for drinking. Depending on the rating of Pollution Index of Groundwater values, groundwater was polluted.
This paper presents studying the performance of three types of polyethersulfone (PES) membrane for the simultaneous removal of Co2+ ions, Cd2+ ions, and Pb2+ ions from binary and ternary aqueous solutions. Co2+ ions, Cd2+ ions, and Pb2+ ions with two different initial concentrations (e.g., 10 and 50 ppm) were selected as examples of heavy metals that contaminate the groundwater as a result of geological and human activities. This study investigated the effect of types of PES membrane and metal ions concentration on the separation process. For the binary aqueous solutions, the permeation flux of the PES2 membranes was higher for the separation process of solutions containing 50 ppm of Cd2+ ions and 10 ppm of Co2+ ions (24.7 L/m2·h) and Pb2+ ions (23.7 L/m2·h). All the metals in the binary solutions had high rejection when their initial concentration was lower than the initial concentration of the other metal present in the same solution. Using PES2, the maximum rejection of Cd2+ ions was 61.3% when the initial concentrations were 50 ppm Pb2+ ions: 10 ppm Cd2+ ions and 55.4% for Pb2+ ions when the initial concentrations were 10 ppm Pb2+ ions: 50 ppm Cd2+ ions. For the ternary aqueous solutions, the rejection and the permeation flux of the PES membranes increased with decreasing the heavy metal initial concentration. Using PES2, the maximum permeation flux was 21.6 L/m2·h when the initial concentration of the metals was 10 ppm; and the maximum rejection of the metals obtained at initial concentration of 10 ppm was 50.5% for Co2+ ions, 48.3% for Cd2+ ions, and 40% for Pb2+ ions. The results of the filtration process using PES2 of simulated contaminated-groundwater indicated the efficient treatment of groundwater containing Co2+, Cd2+, and Pb2+ ions.
Background In chronic immune thrombocytopenic purpura (ITP), rituximab removes the harmful autoantibodies through antibody-dependent cellular cytotoxicity. The response to rituximab in ITP is variable; the effectiveness of rituximab is influenced by the process of activation of effector fragment C gamma receptors (FcγRs). Genetic factors may affect the response to rituximab. Objectives The influence of FcγRIIa (H131R) and FcγRIIIa (V158F) gene polymorphisms on the response to rituximab in ITP. Methods One hundred ITP patients were genotyped for FcγRIIa (H131R) and FcγRIIIa (V158F) gene polymorphisms using the polymerase chain reaction-restriction fragment length polymorphism assay. The response at the end of the third month was assessed by direct platelets count. Polymorphisms were analyzed in relation to the response. Results The mean platelets count at end of weeks 1-4 of rituximab was statistically significantly higher in patients who achieved complete response (CR) than partial response or no response (P-value = .001). Although RR (44.4%) and HR (38.9%) genotypes were observed to be higher in patients who achieved CR compared with the wild (HH) genotype (16.7%), it was not statistically significantly different (P-value = .648). Conclusion The higher platelet count achieved early is predictive for a better response to rituximab later. FCγRIIA polymorphisms did not significantly influence response to rituximab in ITP.
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