Abstract. The Greenland Ice Sheet Project 2 glaciochemical series (sodium, potassium, ammonium, calcium, magnesium, sulfate, nitrate, and chloride) provides a unique view of the chemistry of the atmosphere and the history of atmospheric circulation over both the high latitudes and mid-low latitudes of the northern hemisphere. Interpretation of this record reveals a diverse array of environmental signatures that include the documentation of anthropogenically derived pollutants, volcanic and biomass burning events, storminess over marine surfaces, continental aridity and biogenic source strength plus information related to the controls on both high-and low-frequency climate events of the last 110,000 years. Climate forcings investigated include changes in insolation of the order of the major orbital cycles that control the long-term behavior of atmospheric circulation patterns through changes in ice volume (sea level), events such as the Heinrich events (massi've discharges of icebergs first identified in the marine record) that are found to operate on a 6100-year cycle due largely to the lagged response of ice sheets to changes in insolation and consequent glacier dynamics, and rapid climate change events (massive reorganizations of atmospheric circulation) that are demonstrated to operate on 1450-year cycles. Changes in insolation and associated positive feedbacks related to ice sheets m•y assist in explaining favorable time periods and controls on the amplitude of massive rapid climate change events. Explanation for the exa•t timing and global synchroneity of these events is, however, more complicated. Preliminary evidence points to possible solar variability-climate associations for these events and perhaps others that are embedded in our ice-corederived atmospheric circulation records.

Glaciochemical time series developed from Summit, Greenland, indicate that the chemical composition of the atmosphere was dynamic during the Holocene epoch. Concentrations of sea salt and terrestrial dusts increased in Summit snow during the periods 0 to 600, 2400 to 3100, 5000 to 6100, 7800 to 8800, and more than 11,300 years ago. The most recent increase, and also the most abrupt, coincides with the Little Ice Age. These changes imply that either the north polar vortex expanded or the meridional air flow intensified during these periods, and that temperatures in the mid to high northern latitudes were potentially the coldest since the Younger Dryas event.

Sulfate concentrations from continuous biyearly sampling of the GISP2 Greenland ice core provide a record of potential climate-forcing volcanism since 7000 B.C. Although 85 percent of the events recorded over the last 2000 years were matched to documented volcanic eruptions, only about 30 percent of the events from 1 to 7000 B.C. were matched to such events. Several historic eruptions may have been greater sulfur producers than previously thought. There are three times as many events from 5000 to 7000 B.C. as over the last two millennia with sulfate deposition equal to or up to five times that of the largest known historical eruptions. This increased volcanism in the early Holocene may have contributed to climatic cooling.

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High-resolution, continuous multivariate chemical records from a central Greenland ice core provide a sensitive measure of climate change and chemical composition of the atmosphere over the last 41,000 years. These chemical series reveal a record of change in the relative size and intensity of the circulation system that transported air masses to Greenland [defined here as the polar circulation index (PCI)] and in the extent of ocean ice cover. Massive iceberg discharge events previously defined from the marine record are correlated with notable expansions of ocean ice cover and increases in PCI. During stadials without discharge events, ocean ice cover appears to reach some common maximum level. The massive aerosol loadings and dramatic variations in ocean ice cover documented in ice cores should be included in climate modeling.