This article aims to apply the ultrasound technique in the field of clean technology to protect environment. The principle of sonochemistry is conducted here to degrade pesticides in simulated industrial wastewater resulted from a factory manufacturing pesticides namely diazinon. Diazinon pesticide selected in this study for degradation under high frequency ultrasound wave. Three different initial concentrations of diazinon (800, 1200, and 1800 ppm), at different solution volumes were investigated in to degrade dissolved diazinon in water. Ultrasound device with 1.7 MHz, and 0.044 cm diameter, was used to study the degradation process. It is found that as the concentration of diazinon increased, the degradation is also increasing, and when the solution volume increases, the ability to degraded pesticides decreases. The experimental results showed an optimum condition achieved for degradation of diazinon at 1200 ppm as initial concentration and 50 ml solution volume. Kinetic modeling applied for the obtained results showed that the degradation of diazinon by high ultrasound frequency wave followed a pseudo-first-order model with apparent rate constant of around of 0.01 s(-1).
A microchannel reactor with guideline structure was investigated to carry out sequential reactionseparation. The catalytic reaction between benzyl chloride and sodium sulfide was demonstrated. Under parallel multiphase flow conditions, the catalytic reaction proceeded with phase separation could be ensured. The phase separation performance was enhanced by performing surface modification.
In this study, a naturally occurring zeolitic tuff located in Jordan was investigated as a potential adsorbent for phosphate removal from aqueous solution. Adsorption kinetics and thermodynamics of phosphate adsorption under different temperatures were studied. The pseudo-second-order kinetic model adequately fitted the collected experimental data under different initial ion concentrations. The Langmuir model is found to be successfully fitting the experimental data. Thermodynamic parameters such as Gibbs's free energy change, standard enthalpy change, and entropy change were evaluated and the results indicated that the sorption process is spontaneous, exothermic with small degree of randomness during the sorption process.
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