The difficulties in synthesizing phase pure BiFeO3 are well known. In this letter we are reporting the optimized synthesis conditions for obtaining phase pure BiFeO3 ceramic. The oxide mixing technique followed by leaching with dilute nitric acid has been used for the synthesis. X-ray diffraction pattern indicated that the sample is phase pure. Scanning electron microscopy along with energy dispersive x-ray fluorescence analysis confirmed the chemical homogeneity of the sample. No segregation of the impurity phase in the matrix was detected. Moreover, Bi/Fe atomic ratio is observed to be ∼1. The ferroelectric transition of the sample at 836 °C has been detected by differential thermal analysis.
BiFeO 3 , when forming a solid solution with BaTiO3, shows structural transformations over the entire compositional range. Above 70 mole % of BiFeO3 the structure is rhombohedral and below 4 mole %, it is tetragonal. In between the structure is cubic. The ferroelectric TC decreases with increasing composition of BaTiO3 and a relatively small relaxation is observed. Impedance measurements showed a structural dependence and analysis of which has clearly shown that the capacitance observed is from the bulk of the sample. Relaxation time (τ) of BiFeO3 was estimated using the relaxation times of the intermediate compositions. Magnetization measurements showed field induced ferromagnetism. As the structure becomes cubic with increasing concentration of BaTiO3, paramagnetism sets in, as evidenced by the electron spin resonance spectra.
and are members of the Aurivillius family of compounds having simultaneous electrical and magnetic ordering. Magnetoelectric measurements carried out in a linear time-varying magnetic field with an alternating-current field superimposed yielded a non-linear signal. The shift from linearity, which is not usually observed for antiferromagnetic materials, may be due the tilt in the octahedra. The variation of the magnetoelectric output with temperature for and indicated magnetic anomalies with enhanced sensitivity, corresponding to those in magnetization data.
Following the phenomenological approach of Landau and Lifshitz the existence of linear magnetoelectric effect in antiferromagnetic Cr 2 0 3 was predicted by Dzyaloshinskii which was later experimentally confirmed by Astrov and Folen et al. Magnetoelectric phenomenon has been observed in several single-phase materials in which simultaneous electric and magnetic ordering coexists and in two-phase composites in which the participating phases are the ferroelectric and magnetic. The author's group has recently undertaken a systematic study of the preparation, characterization and detection of the (ME)n output in a few single-phase materials and two-phase composites. This article describes the magnetoelectric phenomenon in general and recent work carried out in the author's group.
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