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By rotating the four-section π-shifted phase plate in the transverse plane relatively to the axes of the elliptical beam of 800-nm, 1.1-mJ, 35-fs pulse propagating in air, we switch between the regime of four parallel plasma channels and the regime of spatial symmetry breakup followed by on-axis plasma channel formation identified on the burnt paper images of the beam. Relaxation of the π-phase shift for 45° phase plate rotation is demonstrated explicitly in 3D+time carrier wave resolved numerical simulations yielding the initial step-like phase distribution degradation along the plasma region. This degradation becomes negligible as the angle between the ellipse major axis and the π-phase break line decreases to 15°.

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Transformations of the low-energy vibrational spectra are associated with structural changes in an analyte and closely related to the instability of weak chemical bounds. Terahertz (THz)/far-infrared optical spectroscopy is commonly used to probe such transformation, aimed at characterization of the underlying solid-phase chemical reactions in organic compounds. However, such studies usually provide quite qualitative information about the temperature- and time-dependent parameters of absorption peaks in dielectric spectra of an analyte. In this paper, an approach for quantitative analyses of the solid-phased chemical reactions based on the THz pulsed spectroscopy was developed. It involves studying an evolution of the sample optical properties, as a function of the analyte temperature and reaction time, and relies on the classical oscillator model, the sum rule, and the Arrhenius theory. The method allows one to determine the temperature-dependent reaction rate V1(T) and activation energy Ea. To demonstrate the practical utility of this method, it was applied to study α-lactose monohydrate during its temperature-induced molecular decomposition. Analysis of the measured THz spectra revealed the increase of the reaction rate in the range of V1 ≃ ~9 × 10−4–10−2 min−1, when the analyte temperature rises from 313 to 393 K, while the Arrhenius activation energy is Ea ≃ ~45.4 kJ/mol. Thanks to a large number of obtained physical and chemical parameters, the developed approach expands capabilities of THz spectroscopy in chemical physics, analytical chemistry, and pharmaceutical industry.

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The development of mobile optoelectronic graders for separating viable seeds by spectrometric properties with high detection accuracy represents a very relevant direction of development for seed handling operations. Here, the main parameters of the radiation source and receiver for detecting a single seed in the diagnostic system of a mobile grader were modeled based on the principles of technical optics using Scots pine (Pinus sylvestris L.) seeds as a case study. Among the pine seeds in the seed batch, there are fossilized and empty seeds that are exactly the same in geometric and gravitational parameters as live seeds. For their separation from the seed batch, data from spectrometric studies in the near-infrared (980 nm) region can be used. To substantiate the parameters of the light source, a geometric optical model of optical beam formation was considered, while the energy model of optical beam formation was considered to substantiate the parameters of the light detector. The results of this study show that the signal value depended on the orientation of a single seed relative to the recording window. The beam angle from the radiation source should be within 45 degrees. The difference between the optical streams should be 50 microns, which made it possible to clearly detect the signal at a standard noise level of 15 microns and signal-to-noise detection accuracy ratio of 56.3 dB. This study expands theoretical knowledge in the field of the spectrometric properties of a single seed, considering the cases of its orientation relative to the optical beam, which affected the effective area of detection of the seed. The obtained data on the location of the main elements of the diagnostic system will speed up the design of mobile optoelectronic graders, and the development of a contemporary protocol for improving Scots pine seed quality.