Aerobic fixed bed bioreactors were used to study and compare biostimulation and bioaugmentation for remediation of soil contaminated with spent motor oil. Bioaugmentation using consortium of bacteria and biostimulation using inorganic fertilizer and potassium dihydrogen orthophosphate were investigated. The bioremediation indicators used were the oil and grease content removals, total heterotrophic bacteria counts and carbon dioxide respiration rates. Results showed that biodegradations were very effective with 50, 66 and 75 % oil and grease content removal efficiencies for control, bioaugmentation and biostimulation respectively after ten weeks. Carbon dioxide respiration followed similar pattern as the oil and grease content removals. Biostimulation option has the highest carbon dioxide generation (6 249 mg/kg) and the control with the least (4 276 mg/kg). Therefore, the biostimulation option can be used to develop a realistic treatment technology for soils contaminated with spent motor oil.

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Some oil and gas reservoirs are often weakly consolidated making them liable to sand intrusion. During upstream petroleum production operations, crude oil and sand eroded from formation zones are often transported as a mixture through horizontal pipes up to the well heads and between well heads and flow stations. The sand transported through the pipes poses serious problems ranging from blockage, corrosion, abrasion, and reduction in pipe efficiency to loss of pipe integrity. A mathematical description of the transport process of crude oil and sand in a horizontal pipe is presented in this paper. The model used to obtain the mathematical description is the modified form of Doan et al. (1996 and 2000) models. Based on the necessity to introduce a sand deposit concentration term in the mass conservation equation, an additional equation for solid phase was derived. Difference formulae were generated having applied Fick’s equation for diffusion to the mass conservation equations since diffusion is one of the transport mechanisms. Mass and volume flow rates of oil were estimated. The new model, when tested with field data, gave 85% accuracy at the pipe inlet and 97% accuracy at the exit of the pipe.

This study presents comprehensive thermoeconomic and thermoenvironomic modeling and analysis of selected gas turbine power plants in Nigeria using the first and second laws of thermodynamics (exergy) concept. Exergetic analysis was conducted using operating data obtained from the power plants to determine the exergy destruction and exergy efficiency of each major component of the gas turbine in each power plant. The results of the study showed that the combustion chamber (CC) is the most exergy destructive component compared to other cycle components. The percentage of exergy destruction in CC varies between 86.05% and 94.6%. By increasing the gas turbine inlet temperature (GTIT), the exergy destruction of this component can be reduced. The total exergy improvement potential of the selected plants varies from 54.04 to 159.88 MW. The component with the highest exergy improvement potential is the CC, which has the value that varies from 30.21 to 88.86 MW. Thermoeconomic analysis showed that the cost of exergy destruction is high in the CC, and an increase in the GTIT effectively decreases this cost. The exergy costing analysis revealed that the unit cost of electricity produced in the plants ranged from cents 1.99/kWh (N3.16/ kWh) to cents 5.65 /kWh (N8.98/kWh). Thermoenvironomic analysis showed that the CO 2 emissions varied between 100.18 and 408.78 kg CO 2 /MWh, while cost rate of environmental impact varied from 40.18 $/h (6, 388.62 N/h) to 276.97 $/h (44, 038. 23 N/h). The results further showed that CO 2 emissions and cost of environmental impact decrease with increasing GTIT. The sustainability index increase with increasing GTIT. Finally, this study will assist efforts to understand the thermodynamic losses in the gas turbine cycle, and to improve efficiency as well as provide future recommendations for better performance, sustainability, and lessening environmental impact of power plant. 424

In this study, performance assessment of selected gas turbine power plants in Nigeria was evaluated using performance indices. The results of the study showed that for the period under review (2006)(2007)(2008)(2009)(2010), the percentage shortfalls from the target energy in the selected power plants range from 26.33% to 86.61% as against the acceptable value of 5-10%. The capacity factor of the selected power plants varies from 16.88% to 73.67% as against the international value of 50-80%. The plant use factor varies from 45.89% to 97.03% and the utilization factor varies from 6.31% to 93.074% as against the international best practice of over 95%. From this result, it can be concluded that the generating units were underutilized. This is due to inadequate routine maintenance and equipment fault development. The analyses of reliability indicators revealed that the mean time between failures varies from 5.42 to 378.44 h, the mean time to repair varies from 18.3 to 153.88 h and the plant availability varies from 12.86% to 91.31% as against the Institute of Electrical and Electronics Engineers recommended standard of 99.9%. Evaluation of operating figures of the selected power plants revealed that starting reliability (SR) and operating reliability vary from 71.95% to 93.9% and 5.33% to 55%, respectively. The SR of the selected power plants is low in value compared with standard value of 99.9%. The statistical analysis carried out on plant availability revealed that at 95% confidence level; there is a significant difference in availability of the selected power plants. This indicates differences in their systems installation, operation and maintenance. The performance indicator developed to evaluate the performance indices for the selected stations can also be applicable to other power stations in Nigeria and elsewhere. Measures to improve the performance indices of the plants have been suggested in this paper.

in Wiley Online Library (wileyonlinelibrary.com).Ideal heat pump performance models containing one adjustable parameter and intensive thermodynamic variables were developed by transformation of the energetic functions of Rankine heat pump. Two unknown groups in the formulated model, labeled AKR and AKF, were found to curve fit to two intensive variables as linear functions. The parameters of the linear fits were obtained using the least square method; consequently, AKR and AKF were expressed as temperature-lift variables. Maximum errors of about 5% were encountered at conditions below reduced temperature of 0.8. Better accuracy was obtained in the range of practical temperature lift (i.e., 10-80 C). Only one fit parameter value is required by these models where similar correlations require three or more. Furthermore, unlike some of the available models where different equations are required for each working fluid, these equations are not working fluid specific and do not require thermodynamic properties' tables or charts.