The effect of the bonding layer type and piezoelectric layer thickness on the magnetoelectric (ME) response of layered poly(vinylidene fluoride) (PVDF)/epoxy/Vitrovac composites is reported. Three distinct epoxy types were tested, commercially known as M-Bond, Devcon, and Stycast. The main differences among them are their different mechanical characteristics, in particular the value of the Young modulus, and the coupling with the polymer and Vitrovac (Fe39Ni39Mo4Si6B12) layers of the laminate. The laminated composites prepared with M-Bond epoxy exhibit the highest ME coupling. Experimental results also show that the ME response increases with increasing PVDF thickness, the highest ME response of 53 V·cm(-1)·Oe(-1) being obtained for a 110 μm thick PVDF/M-Bond epoxy/Vitrovac laminate. The behavior of the ME laminates with increasing temperatures up to 90 °C shows a decrease of more than 80% in the ME response of the laminate, explained by the deteriorated coupling between the different layers. A two-dimensional numerical model of the ME laminate composite based on the finite element method was used to evaluate the experimental results. A comparison between numerical and experimental data allows us to select the appropriate epoxy and to optimize the piezoelectric PVDF layer width to maximize the induced magnetoelectric voltage. The obtained results show the critical role of the bonding layer and piezoelectric layer thickness in the ME performance of laminate composites.
A flexible, low-cost energy-harvesting device based on the magnetoelectric (ME) effect was designed using Fe 64 Co 17 Si 7 B 12 as amorphous magnetostrictive ribbons and polyvinylidene fluoride (PVDF) as the piezoelectric element. A 3 cm-long sandwich-type laminated composite was fabricated by gluing the ribbons to the PVDF with an epoxy resin. A voltage multiplier circuit was designed to produce enough voltage to charge a battery. The power output and power density obtained were 6.4 μW and 1.5 mW cm −3 , respectively, at optimum load resistance and measured at the magnetomechanical resonance of the laminate. The effect of the length of the ME laminate on power output was also studied: the power output exhibited decays proportionally with the length of the ME laminate. Nevertheless, good performance was obtained for a 0.5 cm-long device working at 337 KHz within the low radio frequency (LRF) range.
The magnetoelectric (ME) effect is increasingly being considered an attractive alternative for magnetic field and current sensing, being able to sense static and dynamic magnetic fields.The present work reports on a DC current sensor device based on a ME PVDF/Metglas composite, a solenoid and the corresponding electronic instrumentation.The ME sample shows a maximum ME coefficient (α33) of 34.48V•cm −1 .Oe −1 , a linear response (R 2 =0.998) and a sensitivity of 6.7 mV.A -1 . With the incorporation of a charge amplifier, an AC-RMS converter and a microcontroller the linearity is maintained (R 2 =0.997), the ME output voltage increases to a maximum of 2320 mV and the sensitivity rises to 476.5 mV.A -1 . Such features allied to the highest sensitivity reported in the literature on polymer-based magnetoelectric composites provides the reported ME sensing device suitable characteristics to be used in non-contact electric current measurement, motor operational status checking, and condition monitoring of rechargeable batteries, among others.
Harvesting magnetic energy from the environment is becoming increasingly attractive for being a renewable and inexhaustible power source, ubiquitous and accessible in remote locations. In particular, magnetic harvesting with polymer-based magnetoelectric (ME) materials meet the industry demands of being flexible, showing large area potential, lightweight and biocompatibility. In order to get the best energy harvesting process, the extraction circuit needs to be optimized in order to be useful for powering devices. This paper discusses the design and performance of five interface circuits, a full-wave bridge rectifier, two Cockcroft–Walton voltage multipliers (with 1 and 2 stages) and two Dickson voltage multipliers (with 2 and 3 stages), for the energy harvesting from a Fe61.6Co16.4Si10.8B11.2 (Metglas)/polyvinylidene fluoride/Metglas ME composite. Maximum power and power density values of 12 μW and 0.9 mW cm−3 were obtained, respectively, with the Dickson voltage multiplier with two stages, for a load resistance of 180 kΩ, at 7 Oe DC magnetic field and a 54.5 kHz resonance frequency. Such performance is useful for microdevice applications in hard-to-reach locations and for traditional devices such as electric windows, door locking, and tire pressure monitoring.
The anisotropic magnetoelectric (ME) effect on a Fe 61.6 Co 16.4 Si 10.8 B 11.2 /PVDF Fe 61.6 Co 16.4 Si 10.8 B 11.2 laminate composite has been used for the development of a magnetic field sensor able to detect both the magnitude and direction of AC and DC magnetic fields. The accuracy (99% for both AC and DC sensors), linearity (92% for the DC sensor and 99% for the AC sensor) and reproducibility (99% for both sensors) indicate the suitability of the sensor for applications. Furthermore, the sensitivity of the Fe 61.6 Co 16.4 Si 10.8 B 11.2 /PVDF/ Fe 61.6 Co 16.4 Si 10.8 B 11.2 anisotropic magnetic sensor-15 and 1400 mV Oe −1 for the DC and AC fields, respectively-are the highest reported in the literature for polymer-based ME materials. Such features, combined with its flexibility, versatility, light weight, low cost and lowtemperature fabrication, lead to the suitability of the developed sensor for use in magnetic sensor applications.
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