Measurements of the Balloon Intercomparison Campaign (BIC), conducted during fall, 1982 (BIC-I) and summer, 1983 (BIC-2), are reported.Results of five remote and two in situ techniques agree (with a few exceptions) within 95% confidence level uncertainties and generally within 15% above 20 km. Weighted mean profiles, which best represent conditions during the campaign, are used as a comparison standard.Accuracies of experiments indicated by BIC generally confirm estimated uncertainites for ECC sondes, UV photometry, and microwave emission experiments, are somewhat better for far IR emission and IR absorption experiments, and are somewhat worse for IR emission and solar UV absorption experiments.The large collection of BIC measurements confirms a problem reported earlier with current theoretical modeling of ozone near 40 km where transport is negligible and the chemistry is believed to be simpler.
KEY WORDS.Ozone, intercomparison, balloon, stratosphere. 182 D. ROBBINS ET AL.
During the 1982 and Balloon Intercompaxison Campaigns, the vertical profile of stratospheric NO2 was measured remotely by nine instruments and that of NO by two. Total overhead columns were measured by two more instruments. Between 30 and 35kin, where measurements overlapped, agreement between NO profiles was within :t=30~, which is better than the accuracies claimed by the experimenters. Between 35 and 40kin there was similarly good agreement be~neen NO~ profiles, but below 30kin, differences of greater than a factor three were found. In the second Campaign, NO2 values from most instruments agreed within their quoted errors, except that the Oxford radiometer gave much lower values; but the first Campaign and the column measurements show a more uniform spread of results.These differences below 30km could not be resolved, but new laboratory measurements are planned which should do so.
The Balloon Intercomparison Campaign (BIC) was set up to intercompare remote sensing measurements of a number of compounds other than water vapor; however, water vapor has strong absorption features throughout the infrared and mm wave regions of the spectrum. Therefore many of the investigators involved in BIC have absorption or emission features due to water vapor in the data they obtained during the balloon flights made under the campaign.These features have been used by the investigators to determine the stratospheric water vapor profiles which are compared in this paper. The profiles allow comparison of a wide range of remote sensing techniques involving both emission and absorption in the mid-infrared and emission techniques in the far infrared.
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