1 1 201Poly[2,2'-(m-phenylene)-5.5'-bibenzimidazole] (PBI) is shown to be miscible with poly(4-vinyl pyridine) over the entire composition range. Experiments were performed with commercial PBI as well as a lower molecular weight material synthesized by us. Blend miscibility is evidenced by single glass transition temperature intermediate between the pure polymers. Hydrogen bonding between the components was detected by infrared spectroscopy.
SYNOPSISBlends of commercial poly (amic acid), LARC-PAA polymer were prepared with thermoplastic polyimide P84. The blends were shown to be miscible over a certain composition range. Chemical imidization of LARC-PAA in the blends leads to phase separation. Thermal imidization of LARC PAA in the blends was carried out in the solid state. Miscible compositions of the blend remained miscible after imidization and showed a single glass transition for each blend. Immiscible compositions after imidization remained immiscible and showed two glass transition temperatures in the DSC scans. The kinetics of thermal imidization of PAA to polyimide (PI) in the solid state were studied using FTIR. In the immiscible blend the kinetics remained unaffected while in the miscible state the rate of imidization became faster than that of the pure PAA.
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