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A one‐step procedure is proposed for synthesizing 2‐acyl benzopyrano[2,3‐c]pyrazoles and 2‐aryl benzopyrano[2,3‐c]pyrazoles. The method is based on the condensation of 2‐iminocoumarin‐3‐carbonitriles with hydrazides and hydrazines in acid as catalysts. A mechanism of reaction is proposed. All prepared compounds are identified by FTIR, 1H NMR, 13C NMR, mass spectroscopy, and elemental analysis.

10 Title compounds of type (III) and 18 title compounds of type (VI) or (VIII) are prepared.