We demonstrate a simple synthetic strategy for the fabrication of single-phase rare earth (RE) doped gadolinium oxide (Gd(2)O(3):RE where RE = terbium (Tb), ytterbium (Yb), and erbium (Er)) nanorods (NRs) as multimodal imaging probes. The NRs are ultranarrow and exhibit both emission and magnetic characteristics. The Tb-doped and Yb/Er-codoped Gd(2)O(3) NRs exhibit down- and up-conversion fluorescence respectively, and also exhibit paramagnetism. Importantly, these codoped NRs possess excellent magnetic characteristics, as shown in their longitudinal relaxation time (T1) -weighted image contrast, which is closer to that of commercial Gadovist for magnetic resonance imaging (MRI) applications. This property opens up new avenues in the development of contrast agents.
A sense of cell-being: Single-walled carbon nanotubes (SWNTs) are functionalized with bioactive monosaccharides to enable their use as biosensors. The glycosylated nanotube network is biocompatible and can interface with living cells (see scheme) to electronically detect biomolecular release with high temporal resolution and high sensitivity.
SiO 2 colloid crystal infilled with BaTiO3 was synthesized by a process of self-assembly in combination of a sol–gel technique. It is found that infilling of the fully crystallized BaTiO3 into the colloid assembly can enhance the photonic band gap significantly. In the vicinity of the ferroelectric phase transition point of BaTiO3 (100–150 °C), the photonic band gap of the assembly exhibits a strong temperature dependence. At the Curie point, the band gap has a 20 nm redshift, and the optical transmittance reaches its minimum. Such a temperature-tuning effect in the photonic band gap should be of high interest in device applications.
ZnS:Mn has been in-filled in photonic crystals of submicron polymer spheres. The effect of the photonic band gap on the photoluminescence (PL) properties of ZnS:Mn has been investigated. Because of the overlap of the transmission dip of the photonic crystal and the photoluminescence band of ZnS:Mn, both suppression and enhancement in the PL of the phosphor have been observed. A strong dependence of the fluorescence lifetime on the emission wavelength in the range of the stop band has been found. This strong dependence is believed to arise from the very low photon density of state within the stop band of the ZnS:Mn in-filled photonic crystal as result of a high dielectric contrast between ZnS:Mn and the polystyrene spheres.
A sense of cell‐being: Single‐walled carbon nanotubes (SWNTs) are functionalized with bioactive monosaccharides to enable their use as biosensors. The glycosylated nanotube network is biocompatible and can interface with living cells (see scheme) to electronically detect biomolecular release with high temporal resolution and high sensitivity.
A three-dimensional photonic band gap structure based on self-assembled crystals of polystyrene microspheres was fabricated by filling the pores with metallic silver. An almost complete stop band at 580–600 nm is observed in the optical transmission spectra. In comparison with pure polystyrene colloid crystals, the absorption band of Bragg diffraction in the composite was much more intense and broader, due to an enlargement of the contrast between the spheres and the background. A shift to shorter wavelengths in the band occurred because of a decrease in the average refractive index.
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