Abstract— Using new techniques to examine the products of space weathering of lunar soils, we demonstrate that nanophase reduced iron (npFe0) is produced on the surface of grains by a combination of vapor deposition and irradiation effects. The optical properties of soils (both measured and modeled) are shown to be highly dependent on the cumulative amount of npFe0, which varies with different starting materials and the energetics of different parts of the solar system. The measured properties of intermediate albedo asteroids, the abundant S‐type asteroids in particular, are shown to directly mimic the effects predicted for small amounts of npFe0 on grains of an ordinary chondrite regolith. This measurement and characterization of space weathering products seems to remove a final obstacle hindering a link between the abundant ordinary chondrite meteorites and common asteroids.

Abstract— Interior samples of three different Nakhla specimens contain an iron‐rich silicate “rust” (which includes a tentatively identified smectite), Ca‐carbonate (probably calcite), Ca‐sulfate (possibly gypsum or bassanite), Mg‐sulfate (possibly epsomite or kieserite), and NaCl (halite); the total abundance of these phases is estimated as <0.01 weight percent of the bulk meteorite. Rust veins are truncated and decrepitated by fusion crust and are preserved as faulted segments in partially healed olivine crystals, indicating that the rust is pre‐terrestrial in origin. Because Ca‐carbonate and Ca‐sulfate are intergrown with the rust, they are also indicated to be of pre‐terrestrial origin. Similar textural evidence regarding origins of the NaCl and Mg‐sulfate is lacking. Impure and poorly crystallized sulfates and halides on the fusion crust of the meteorite suggest leaching of interior (pre‐terrestrial) salts from the interior after Nakhla arrived on Earth but coincidental addition of these same salts by terrestrial contamination cannot be excluded. At least the clay‐like silicate “rust,” Ca‐carbonate, and Ca‐sulfate were formed by precipitation from water‐based solutions on the Nakhla parent planet although temperature and pressure conditions of aqueous precipitation are unconstrained by currently available data. It is possible that aqueous alteration on the parent body was responsible for the previously observed disturbance of the Rb‐Sr geochronometer in Nakhla at or near 1.3 Ga.

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All of the Apollo 16 regolith breccias (18 specimens) have been characterized in terms of their petrography, grain‐size distribution, porosity, major and trace element composition, noble gas contents, and ferromagnetic resonance properties. These breccias vary significantly with respect to their density and porosity, with the more dense breccias showing significant shock damage. The regolith breccias resemble the soils in grain‐size distribution and in the relative proportions of major petrological components, except agglutinates. Many of the breccias are compositionally different from the Apollo 16 soils in that they lack an important mafic component present in the soils. Although some groupings occur, the petrologic and chemical compositions of the regolith breccias do not correlate with the station location of the samples. All but one of the breccias show some evidence of irradiation at the lunar surface (solar gases, measurable FMR, agglutinates), and analyses made on grain‐size separates from two disaggregated breccias indicate that this irradiation occurred before compaction when the breccia material was finely disseminated on the surface. However, the concentrations of surface irradiation parameters (solar gases, FMR, agglutinates) for most breccias are far less than seen in any lunar soils or in regolith breccias from other Apollo missions. Several breccias also contain unusually high trapped 40Ar/36Ar ratios of ∼8–12 and a significant fission Xe component in excess of that expected from in situ production. These observations suggest that the surface irradiation of these breccias occurred as early as 4×109 years ago. We conclude that most of the Apollo 16 regolith breccias were not formed from any known Apollo 16 soil. They appear to be well‐comminuted material that contains ancient regolith developed during the late stage heavy bombardment of the moon when large impacts were much more common relative to small impacts so that regoliths did not have time to significantly mature before being diluted by fresh ejecta and buried. This ancient megaregolith is significantly different from more recent lunar regolith but may be similar to asteroidal regoliths from which some brecciated meteorites have formed.

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