Liquid phase functionalisation of carbon nanotubes is carried out via a H 2 SO 4 + HNO 3 mixture, and the effect of the sulphuric to nitric acid volume ratio (1:3-3:1) is systematically investigated by means of complementary techniques, observing the expected progressive downgrade of the crystalline quality, along with the increase of oxygenated functionality concentration. In addition, in contrast with common expectations, the results obtained demonstrate that the concentration of carboxylic groups (acids and anhydrides) never exceeds that of all other functionalities (lactones, phenols, quinones/carbonyls and sulphonic groups) introduced by chemical oxidation. Only by using equal volumes of sulphuric and nitric acids the concentrations of carboxylic and non-carboxylic groups become comparable. Raman analysis reveals that a change in the sample homogeneity accompanies the variations of the relative proportions of the various oxygenated groups, by the typology of which the vibration modes of carbon pairs and carbon rings appear to be affected to different extents.

Sorption kinetics of pollutant oils, such as kerosene, virgin naphtha, crude oil, and pump oil, into porous siloxanic foams filled with carbon nanotubes (CNTs) are investigated. Both, pristine and functionalized, CNTs are used as foam fillers. Among all, the foam filled with pristine CNT shows a poor affinity with water and high sorption rate in light oils, in which it achieves the highest absorption values (7991 mg g−1 after 660 s and 6685 mg g−1 after 420 s, respectively, in virgin naphtha and kerosene). The kinetic data are described by the pseudo‐first order, pseudo‐second order, Elovich and intraparticle diffusion models. Results show that chemisorption processes are rate limiting the sorption step. In fact, pseudo‐second order model better represents the equilibrium isotherm data. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47374.

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The term soil reinforcement is conventional since decades ago for the stabilization of soft ground such as of clay and peat. Numerous research has arisen in the utilization of natural fibres as the reinforcement materials. Cost reduction, increment of sustainability awareness and eco-friendly environment are some of the advantages when using natural fibres to stabilize soft ground. A research study was carried out to evaluate the strength of the soft soil when unreinforced and reinforced using natural fibres. The findings on the experimental investigation of the study will be presented in this paper. Crushed coir fibres were used to reinforce an intermediate plasticity soft clay where both materials were collected locally in Brunei Darussalam. The crushed coir fibres were added at 0.5%, 1.0%, 1.5% and 2.0% to the dry weight of the sample. A series of an unconsolidated undrained Tri-axial test was conducted on the unreinforced and reinforced samples where the behaviour of the samples were observed and compared. The results indicated that inclusion of fibres affects the soil’s undrained shear strength. It was observed that increasing the percentage inclusion increases the undrained shear strength of the soil, up to a certain amount. Further increment of fibres, however, does not show further improvement in the undrained shear strength.