We have determined the vibrational properties of a sodium tetrasilicate (Na 2 Si 4 O 9 ) glass model generated by molecular dynamics simulations. The study has been carried out using a classical valence force fields approach as well as an ab initio approach in the framework of the density functional theory. The total and partial vibrational densities of states (VDOS) are presented, as well as some characteristics of the vibrational modes (participation ratios, correlation lengths). For the low-frequency bands below 500 cm −1 , we find that the shapes of the two calculated VDOS as well as those of their corresponding partial VDOS are quite similar. For the intermediate-and high-frequency ranges, we observe larger discrepancies between the two calculations. Using the eigenmodes of the dynamical matrix we also calculate the polarized Raman spectra within the bond-polarizability approximation. We find an overall agreement between the calculated parallel polarized (VV) Raman spectra and the corresponding experimental spectrum. Regarding the perpendicular depolarized (VH) Raman spectrum, the comparison of the calculated spectra to the experimental data indicates a need for an adjustment of the VH bond-polarizability parameters.
International audienceXANES spectra were collected at the Si-, Al-, and Na K-edge in hydrous silicate glasses to understand the effect of water on the local structure around these cations. Around network forming Si and Al, no drastic changes are observed. Around Na, the dissolution of water creates more ordered environments in Al-bearing glasses and less ordered environment in Al-free glasses. Ab-initio XANES calculations were undertaken to understand the structural origins for these features. Based on these results, a bond valence model was refined that considers not only the present XANES experiments and models but also NMR information. The double percolation model refined explains, among others, the explosive properties of water-bearing hydrous melts, at the origin of a number of cataclysmic eruptions in subduction zones
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