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Sodium dioctylsulfosuccinate (AOT) micelle has a special counterion binding behavior in aqueous electrolyte medium, viz., the counterion binding constant (β) abruptly increases by 2-fold at about 0.015 mol dm(-3) NaCl concentration (c*), but not in sodium salicylate (NaSa) solution. Since counterions affect the structure and performance of ionic surfactants, ascertaining the cause for the sudden shift in the β value of AOT micelle is of fundamental importance. In this study the special counterion binding behavior of AOT micelle has been ascertained at 40 °C by carrying out surface tension, zeta potential, and fluorescence emission (pyrene probe) measurements. The results of the small-angle neutron scattering experiment carried out at 40 °C showed that at c* the shape of AOT micelle changes from prolate spheroid to rodlike in NaCl solution, but not in NaSa solution, thus establishing micellar shape change as responsible for the abrupt change in β value. The absence of sudden shift in β of AOT micelle in NaSa solution is attributed to the binding of salicylate coanion to AOT micelle through hydrophobic interaction.

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In this investigation, a magnetohydrodynamic (MHD) flow of AlO /water nanofluid and Cu-AlO /water hybrid nanofluid through a porous channel is analyzed in the presence of a transverse magnetic field. An exact solution of the governing equations has been obtained in closed form. The entropy generation number and the Bejan number are also obtained. The influences of each of the governing parameters on velocity, temperature, entropy generation and Bejan number are displayed graphically and the physical aspects are discussed. In addition, a comparison of the heat transfer enhancement level due to the suspension of AlO and Cu nanoparticles in water as regular nanofluids and as hybrid Cu-AlO /water nanofluid is reported.

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This paper is concerned with the entropy generation in a magnetohydrodynamic (MHD) pseudo-plastic nanofluid flow through a porous channel with convective heating. Three different types of nanoparticles, namely copper, aluminum oxide and titanium dioxide are considered with pseudo-plastic carboxymethyl cellulose (CMC)-water used as base fluids. The governing equations are solved numerically by shooting technique coupled with Runge-Kutta scheme. The effects of the pertinent parameters on the fluid velocity, temperature, entropy generation, Bejan number as well as the shear stresses at the channel walls are presented graphically and analyzed in detail. It is possible to determine optimum values of magnetic parameter, power-law index, Eckert number and Boit number which lead to a minimum entropy generation rate. ª 2015 Production and hosting by Elsevier B.V. on behalf of Faculty of Engineering, Alexandria University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/ licenses/by-nc-nd/4.0/).

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