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The preparations and characterizations of several monomeric vinylimidazolium salts are presented from the quaternizations of 1-vinylimidazole and 2-methyl-l-vinylimidazole with n-alkyl iodides and with dimethyl sulphate. Although vinylimidazolium salts have been reported in the patent literature, many of these salts were not isolated and characterized prior to their polymerization. From the reactions of 1-vinylimidazole with n-alkyl iodides, a homologous series of 3-n-alkyl-l-vinylimidazolium iodides were prepared in which the longer chain derivatives appeared to form micelles in aqueous solution. Dicationic crosslinking agents were also prepared through similar quaternization reactions. All the cationic vinyl monomers were homopolymerized in aqueous solution by free radical initiation. The solution behaviour of the resulting polyions indicated that the longer side-chain polyions had polysoap properties. (0.10 mol) of freshly distilled 1-vinylimidazole was added 85.20g (0-60mol) of reagent grade methyl iodide in 100ml of dry ethyl acetate at-10°C. The reaction mixture was stirred for 1 h and then brought to room

Copolymerization studies of cationic monomers have been reported in the literature to yield wide variations in reactivity ratios and Q–e values, depending on the comonomer and the nature of the solvent. In this work are presented the copolymerization characteristics of a variety of vinylimidazolium salts in both water and ethanol solution. From these studies, the effect of solvent polarity, of substitution at the imidazolium 2‐position, of the type of counterion, and of the hydrophilic–hydrophobic character of the monomeric salts could be ascertained. The results of the study are consistent with other related investigations, in that solvent polarity and comonomer both strongly affected copolymerization.