No abstract

Oxygen isotope ratios of well-preserved brachiopod calcite and conodont apatite were used to reconstruct the palaeotemperature history of the Middle and Late Devonian. By assuming an oxygen isotopic composition of 1‰ V-SMOW for Devonian seawater, the oxygen isotope values of Eifelian and early Givetian brachiopods and conodonts give average palaeotemperatures ranging from 22 to 25 C. Late Givetian and Frasnian palaeotemperatures calculated from d 18 O values of conodont apatite are close to 25 C in the early Frasnian and increase to 32 C in the latest Frasnian and early Famennian. Oxygen isotope ratios of late Givetian and Frasnian brachiopods are significantly lower than equilibrium values calculated from conodont apatite d 18 O values and give unrealistically warm temperatures ranging from 30 to 40 C. Diagenetic recrystallization of shell calcite, different habitats of conodonts and brachiopods, as well as non-equilibrium fractionation processes during the precipitation of brachiopod calcite cannot explain the 18 O depletion of brachiopod calcite. Moreover, the 18 O depletion of brachiopod calcite with respect to equilibrium d 18 O values calculated from conodont apatite is too large to be explained by a change in seawater pH that might have influenced the oxygen isotopic composition of brachiopod calcite. The realistic palaeotemperatures derived from d 18 O apatite may suggest that biogenic apatite records the oxygen isotopic composition and palaeotemperature of Palaeozoic oceans more faithfully than brachiopod calcite, and do not support the hypothesis that the 18 O/ 16 O ratio of Devonian seawater was significantly different from that of the modern ocean.

Oceanic 87 Sr/ 86 Sr-isotope ratios are strongly influenced by rates of silicate weathering and therefore linked not only to glaciation but also to sea-level change. The present study combines analysis of sequence stratigraphy and basin architecture with Sr-isotope stratigraphy in Miocene shallow-water sediments in southern Portugal and Crete (Greece). The common method is to use smoothed global sea water Sr-isotope reference curves but here a different approach is chosen. Instead, measured Sr-isotope curves are correlated with unsmoothed reference curves by identification of similar fluctuations in the order of several 100 kyr. Transgressive intervals are characterized by increasing Sr-isotope ratios interpreted as corresponding to intensified silicate weathering as a consequence of deglaciation, while lowstand deposits have low Sr-isotope ratios. Comparison of Sr-isotope curves and sedimentary sequences in the studied basins with independent global d 18 O data and data on global sea-level might suggest a general relationship, supporting a connection to global climate change. Because of these relationships, the method presented herein has a high potential for use in high-resolution age dating and is also applicable in shallow-water sediments.