Shape‐controlled metal nanocrystals, such as nanowires and nanoflowers, are attractive owing to their potentially novel catalytic properties and bimetallic nanocrystals composed of two distinct metals are expected to act as highly active catalysts. However, their catalytic activities are limited because of the capping agents adsorbed on the metal surfaces, which are necessary for the preparation and dispersion of these nanocrystals in solvents. Therefore, the preparation of bimetallic shape‐controlled noble metal nanocrystals with clean surfaces, devoid of almost all capping agents, are expected to have high catalytic activity. Herein, we report the preparation of bimetallic Au–Ag nanoflowers using melamine as the capping agent. The bimetallic Au–Ag nanoflowers with a clean surface were subsequently obtained by a support and extraction method. The bimetallic nanoflowers with a clean surface were then used for the aerobic oxidation of 1‐phenylethyl alcohol and they exhibited high rates for the formation of acetophenone compared to Au nanoflowers and spherical nanoparticles with almost the same size and Au/Ag ratio. We also show that Au–Ag nanoflowers containing only 1 % Ag (Au99–Ag1NFs) exhibit the highest rate of acetophenone formation among Au–Ag nanoflowers with different Au/Ag ratios owing to an increase in the electron density of the Au atoms that act as active sites for the oxidation of 1‐phenylethyl alcohol.
The oxidation of Ag nanostructures has been studied as a key step for their degradation under the guiding principle in the previous paper that they are stable when their Fermi level is lower than those of their surroundings. The drop of the Fermi level of a thin Ag layer was caused by the formation of self-assembled monolayers (SAMs) of certain organic compounds including those of photographic interest and a monolayer of AgI, and attributed to the formation of dielectric layers, whose positive charges were closer to the Ag layer than negative charges. A consideration is given on further examinations needed to realize the above guiding principle in individual devices.
We have investigated a dielectric–metal–dielectric (DMD) multilayer film, which is unique as compared with such conventional transparent conductive oxides as indium tin oxide (ITO). In this study, we have selected MoO3 and Ag as the dielectric material and metal, respectively, and employed a nano-mist method in addition to a vacuum evaporation one. The transmission spectra of the films indicated that the Ag morphology changed from isolated islands to continuous layers with increasing Ag layer thickness, and that the morphology change was enhanced by MoO3. Then, MoO3/Ag/MoO3 (MAM) multilayer-structured transparent electrodes could be fabricated by a nano-mist method as well as by a vacuum evaporation one. Comparative examination is made on the properties of MAM films fabricated by these two methods for their application.
Nanoflowers
(NFs)shape-controlled noble metal nanocrystalshave
garnered significant attention because of their novel catalytic properties
and applicability. In this paper, we report the preparation and catalytic
performance of a magnetic Fe3O4-supported AuNF
catalyst with a clean surface. The magnetically supported AuNFs were
obtained by using magnetic Fe3O4 as the support.
However, when nonmagnetic γ-Al2O3 was
utilized as the support, the AuNFs did not exhibit a magnetic response.
These supported AuNFs were utilized to catalyze the oxidation of 1-phenylethyl
alcohol to acetophenone using air (1 atm) as the oxidant. The rate
of formation of acetophenone using supported AuNFs was 8-fold higher
than that of acetophenone using supported spherical Au nanoparticles
of comparable size. In addition, the Fe3O4-supported
AuNFs exhibited a higher rate of formation of acetophenone than the
Al2O3-supported AuNFs. The Fe3O4-supported AuNFs were recovered using a magnet, and the recovered
catalyst was reused under identical catalytic reaction conditions.
The rate of formation of acetophenone using recovered Fe3O4-supported AuNFs remained unchanged, demonstrating no
loss of catalytic activity.
Several digital watermarking techniques for audio files have been proposed for hiding data for protecting their copyrights. There is a tradeoff between the quality of watermarked audio and the tolerance of watermarks to signal processing methods, such as compression. To overcome the inevitable tradeoff, we previously developed an authentication method for digital audio. We have improved the method by determining the region to be authenticated in the audio data by making effective use of the fundamental frequency characteristics.
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