We investigated characteristics of impurities and their impact on the ablation of Glacier No.31 in the Suntar-Khayata Mountain Range in Russian Siberia during summer 2014. Positive degree-day factors (PDDFs) obtained from 20 stake measurements distributed across the glacier's ablation area varied from 3.00 to 8.55 mm w.e. K −1 day −1 . The surface reflectivity measured with a spectrometer as a proxy for albedo, ranged from 0.09 to 0.62, and was negatively correlated with the PDDF, suggesting that glacier ablation is controlled by surface albedo on the studied glacier. Mass of total insoluble impurities on the ice surface varied from 0.1 to 45.2 g m −2 and was not correlated with surface reflectivity, suggesting that albedo is not directly conditioned by the mass of the impurities. Microscopy of impurities revealed that they comprised mineral particles, cryoconite granules, and ice algal cells filled with dark-reddish pigments (Ancylonema nordenskioldii). There was a significant negative correlation between surface reflectivity and algal biomass or organic matter, suggesting that the ice algae and their products are the most effective constituents in defining glacier surface albedo. Our results suggest that the melting of ice surface was enhanced by the growth of ice algae, which increased the melting rate 1.6-2.6 times greater than that of the impurity free bare-ice.
We developed an environmentally benign Ritter reaction of alcohols with nitriles using a commercially available bismuth salt as a less harmful catalyst. The detailed reaction profiles revealed that consumption of the ether by‐product as the reaction proceeded was the key for optimizing this reaction, and the yield of the target amide was improved by adding a small amount of water. This finding clearly reveals the significance of using a bismuth salt as the catalyst, as it is not deactivated in the presence of water. This catalyst system has a broad substrate scope, and even with 1 mol‐% of the catalyst, the reaction progresses smoothly. It is also possible to react stoichiometric amounts of nitriles and alcohols, thus reducing the amount of organic solvent required for the reaction. Furthermore, as the inexpensive bismuth catalyst can be easily removed using aqueous hydrochloric acid, a purification process that only required washing and drying without any organic solvents was successfully established.
ThispaperoutlinesmeteorologicalandglaciologicalobservationsofGlacierNo.31intheSuntar-Khayata Range,eastSiberia,obtainedfrom2012to2014.Wesetupmeteorologicalinstrumentsandsevenstakeson theglacierforthepurposeofmeasuringsurfacemassbalanceandflowvelocity.Themeanairtemperature between July 8, 2012 and August 7, 2013 was-13.9 at site 31-2 (2446m a.s.l.) and the minimum temperaturewas-46.0 .TheairtemperatureontheglacierfromNovembertoAprilwasapproximately 10 higherthanthatatOymyakonvillage,suggestingatemperatureinversionphenomenon,whichtypically occursduringwinterinthisregion.Thesnowdepthrecordsshowthatsnowincreasedatthebeginningand endofwinter,andthattherewasalmostnochangefromthebeginningofOctoberuntiltheendofApril. The maximum snow depth from the previous summer was 158cm at site 31-2 on May 28, 2013. The averageannualsurfacemassbalanceforthe6siteswas-1256mmwaterequivalent(w.e.)duringtheperiod from August 24, 2012 to August 16, 2013, indicating that ablation proceeded rapidly in all areas of the glacier.Surfaceflowvelocityin2013/2014was1.57ma −1 attheapproximatemidpointoftheglacier,andwas much slower than that measured during the IGY (International Geophysical Year) period (4.5ma −1) in 1957/1958.Thelengthandarealextentoftheglacierwere3.85kmand3.2km 2 in1958/1959and3.38kmand 2.27km 2 in2012/2013,respectively,showingadecreaseoverthelast54years.
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