This paper proposes a novel approach for full duplex using chaotic sequences which is known as the asynchronous code-division duplex (Async-CDD) system. The Async-CDD system can transmit and receive signals at the same time and in the same frequency channel without time slot synchronization. The data rate of the Async-CDD system is 8 times higher than the conventional CDD system and is the same as a non-spreading system. The property of low block cross-correlation of the chaotic sequence allows the Async-CDD system achieve duplex interference suppression at any duplex delay. And the huge number of available code words/blocks of the chaotic sequence allows the Async-CDD system increase the data rate by increasing the number of multiplexed sub-channels. When both of the code length of the orthogonal chaotic code and the number of multiplexed sub-channels are 128, the orthogonal chaotic code provides 30.40 dBc self-interference suppression in average, which is 6.99 dB better than the orthogonal Gold code.
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