This paper provides a convenient and simple method for fabricating a self-organized two-dimensional (2D) array of gold nanoparticles on a silicon substrate. The silicon substrate, modified with an aminopropyltriethoxylsilane(APTES) monolayer, was first exposed to a gold colloidal suspension to deposit the gold particles and form a submonolayer of gold nanoparticles. This was followed by treatment with an alkanethiol solution, and then this randomly scattered submonolayer of nanosized gold particles on the silicon substrate was organized into small patches of 2D nanoparticle aggregates. Finally an alcohol solvent was used to drive these small patches of gold nanoparticle aggregates to self-organize together and form continuous ordered arrays on the silicon surface. The SEM images of the samples show that ordered two-dimensional arrays of gold nanoparticles are formed over a very large area and that the nanoparticles are highly organized and formed hexagonally closed packed structured arrays. This highly organized structure of gold nanoparticles can be reproduced over a large area by these effective procedures. Therefore, it is believed such procedures hold promise as an advanced new approach to construct ordered mesoscopic structural materials or for the controlled self-assembly of nanoparticles and could provide the possibility of detecting the collective physical properties of the ensemble.

A porphyrin covalently appended monolayer film on a glass substrate prepared by axial coordination reaction of protoporphyrin IX zinc (ZnPP) and a self-assembled monolayer of (3-aminopropyl)trimethoxysilane on a glass surface was reported. The structure and stability of the porphyrin film to photo reaction, acid, and base and its reactivity with imidazole were investigated using X-ray photoelectron spectroscopy and UV−visible spectroscopy.

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A novel heterojunction photocatalyst p-LaFeO3/n-Ag3PO4 has been prepared via a facile in situ precipitation method. It exhibits higher activity than individual Ag3PO4 and LaFeO3 in the degradation of phenol. The excellent activity is mainly attributed to its more effective separation of electron-hole pairs.

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We, for the first time, demonstrated using experiments and density functional theory (DFT) calculations that high-spin CoII exhibits excellent Fenton-like activity.

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