Excessive nitrogen (N) fertilizer application and poor timing of N fertilizer application to winter wheat are common problems on the North China Plain. To study the possibilities of optimizing the timing and rate of N application, a field experiment was conducted from 1999 to 2001 in a suburb of Beijing. A control (no nitrogen) and two N fertilization strategies (conventional N application and optimized N fertilization) were designed to compare their effects on wheat growth, N nutrient status, grain yield and N balance. The conventional N fertilization strategy was given a fixed N rate of 300 kg N ha À1 , which was split, half in autumn and half in spring as a top-dressing. The timing and rate of N and application of the optimized N fertilization strategy were determined by the target value of soil mineral nitrogen demand for three growth periods of wheat, which is related to the target yield, and soil mineral N (N min ) in the effective rooting depth at the beginning of these three periods. Based on the optimized N fertilization strategy, a total of 55 and 65 kg N ha À1 had to be applied to winter wheat in the re-greening and shooting stages of the first and second experimental years, respectively. Compared with the high N rate before sowing in the conventional N fertilization treatment, the optimized N fertilization treatment did not require any N fertilizer before sowing of wheat. Despite a much lower N fertilization rate, no significant difference in N nutrient status, growth during the wheat growing period or grain yield was observed between optimized N and conventional N fertilization treatments. As a consequence of optimizing the rate and timing of the N fertilizer application to match wheat demand, a much lower residual N min and calculated apparent N loss was found as compared to the conventional N treatment. N recovery for the optimized N fertilization treatment (67% in 1999/2000 and 66% in 2000/2001) was much higher than that of the conventional N fertilization treatment (19% in 1999/2000 and 18% in 2000/2001). In conclusion, the optimized N fertilization strategy can synchronize N demand of wheat and the N supply from soil and fertilizer, and therefore drastically reduce N application rates without any yield losses.

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Phytoremediation is often discussed as a means of extracting trace metals in excess in the soil, but to increase its efficiency a better understanding of the factors controlling plant uptake is required. The main objective of this study was to examine the effect of origin (anthropogenic vs. geogenic) and mobility of thallium (Tl) in the rhizosphere on Tl uptake. Two Tl-hyperaccumulating Brassicaceae species, kale (Brassica oleracea acephala L. cv. Winterbor F1) and candytuft (Iberis intermedia Guers.), were grown in a rhizobox system to investigate the dynamics of Tl in the rhizosphere soil. Four different soils were used. Two soils contained high Tl amounts due to anthropogenic sources (emissions from a cement plant and mining activities). High Tl content in the two other soils was due to a high rock content (geogenic origin). On completion of growth in the rhizoboxes, the depletion of Tl in seven different chemical fractions, determined by sequential extraction, was compared to the plant uptake. Most of the Tl taken up was derived from the so-called "easily accessible" fractions in both soils with geogenic Tl as well as in the soils polluted by mining activities. Due to the small amounts of easily accessible Tl in the geogenic soils, Tl uptake by Brassicaceae was low. On the other hand, for the air emission-polluted soil, a high depletion of Tl from "less accessible" fractions was observed in addition to depletion of the easily accessible fractions. Hence, the latter soil demonstrated the highest potential for effective soil decontamination by phytoextraction within an appropriate time frame.

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