The aim of this study is to determine the potentials of clinoptilolite zeolite in removing selected heavy metals, that are copper and magnesium in aqueous solutions. The removal of both metal cations has been studied by using the batch techniques. Three experimental variables were carried out under predetermined conditions of contact time (20 – 100 minutes), effect of dosage (0.20 – 1.00 gram), and effect of pH solution (pH 2 to 10). Adsorption capacity of zeolite towards heavy metal removal was then determined at various initial concentrations of metal ions between 20 to 100 ppm. Results obtained shows that adsorption of Cu 2+ and Mg 2+ on zeolite has been shown to depend significantly on the pH, adsorbent amount and contact time. The significant value of pH was reached at pH 6, followed by 1 hour of contact time for 1 gram of adsorbent; for both metal ions studied. Studies on the rate of uptake of heavy metal ions by the zeolite indicated that the process was quite rapid and maximum adsorption occurred within the first hour of contact. The results show that high silica zeolite such as clinoptilolite is a promising adsorbent as they combine high adsorption capacities and molecular sieve properties.
The adsorption capacity of activated clinoptilolite zeolite for the removal of heavy metal ions; iron Fe(III) and manganese Mn(II) from palm oil mill effluent (POME) was investigated in this batch sorption study. The physicochemical properties of both raw clinoptilolite zeolite and POME effluent were first characterized before the modification of the zeolite is made, chemically and physically. The raw filtered POME has an initial pH of 4.56 which was acidic, whereas the natural zeolite has a slightly alkaline pH at 7.52. The effects of pH (5, 7 and 9), sorbent dosage (15, 20 and 25 g in 125 ml of effluent), contact time (15, 30, 45, 60, 120, 150, 180 and 200 minutes) and agitation speed (120, 150, 180 and 200 rpm) on the sorption of heavy metal ions were evaluated. The concentration of heavy metals was analyzed using AAS. The concentration of heavy metal ions for each parameter has decreased significantly after batch study. The adsorption of heavy metal ions increased with the increasing of pH and adsorbent dosages. Optimum percentage of metal removal and the amount of metal ions adsorbed by the zeolite were determined at 85% of Fe(III) and almost 92% of Mn(II) in the experiments.
The aim of this work was to investigate the effect of surface treatment on rice husk reinforced recycled high density polyethylene (rHDPE) composites. Three types of surface treatment on rice husk were carried out which were maleated treatment, alkaline treatment and acrylic acid treatment. The characteristics and mechanical properties of the composites were analysed. The results for all treatments showed that tensile strength and break elongation of composites decreased significantly when the rice husk filler loading increased. Further findings showed that maleated treatment on rice husk can further enhance the mechanical properties due to the present of ester bond formed in FTIR analysis.
Rice husk was used as a silicate source to produce RHA-based zeolites through hydrothermal method. The synthesis of zeolite undergone different types and concentrations of alkaline solutions which were 3M and 5M of sodium hydroxide (NaOH) and 5M of potassium hydroxide (KOH), respectively. The rice husk ash and resulted zeolites were then being characterized by X-ray fluorescence (XRF), Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) analyses. Analyses of XRF, SEM and BET results shown that RHA has high content of silica (83.90%) with irregular particles due to large surface area of 48.7 m2g-1. For FTIR analysis, RHA at band 1040.52 cm-1 assigned to asymmetric Si-O-Si bond stretching in SiO4 tetrahedron. The band at 794.71 cm-1 was corresponded to the stretching vibrations quartz of Si-O-Si. Subsequently, the zeolites were applied as an adsorbent in sugarcane bagasse wastewater and tested for total suspended solid (TSS) and chemical oxygen demand (COD). The adsorption capacity of TSS, COD and colour by the previous synthesized zeolites was then observed experimentally through the effects of contact time. Results indicated that adsorption capacity for COD is 13% to 22% and ranged from 50% to 57% for TSS.
Water is a limited resource for Perlis state. Domestically, meeting the water supply in the state requires improving the current supply facility and repairing water leakages in the supply system. However, an even more important aspect of water resources management is the water consumption from agricultural activities such as the over-irrigation in the crop field. This study identifies the soil series of Perlis state, determines its soil textures, estimates the field capacity, permanent wilting point, and plant available water. Additionally, the water infiltration studies were carried out. Results showed there were ten soil series present in the state, and this soil can be categorized by four soil textures that the clay soil texture dominates in seven soil series. Fully saturated soil in the Perlis state potentially losses 27-56% of its soil moisture content drains by gravity, which is unavailable to crop consumption, hence, wastage. An estimated 1.7 x 10-4 to 2.1 x 10-3 m/s water infiltration rate over the soil depths from 0.15-1.5 m. Knowing the soil surface area for the crop field allows the estimate of water volume needed in a unit time needed for storage tank estimation and distribution system designs. The water requirement increases by including the water evaporation rate into the water infiltration rate.
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