Hyporheic exchange, enhanced by complex stream channel morphology, can influence biogeochemical processing in the streambed. These processes chemically alter water passing temporarily through the streambed, which eventually returns to the stream channel and can potentially affect surface water quality. To assess the degree of biogeochemical cycling induced by complex streambed morphology, we instrumented two 20-m reaches of Red Canyon Creek, Wyoming, each containing a small log dam, with in-stream minipiezometers and temperature data loggers. We simultaneously observed pore water geochemistry and streambed temperature dynamics in several bedforms located upstream or downstream of the dams. We modeled seepage flux into the streambed using heat transport modeling. Upstream of the dams, low-permeability sediments have settled out in low-velocity pools, and enhanced anaerobic biogeochemical cycling occurred in the streambed. Rapid flux into the streambed occurred in glides immediately above the dams, where streambed temperature dynamics and geochemistry were nearly identical to the stream. In riffle sequences downstream of the dams, the streambed was oxygen rich, showed evidence of nitrification, and temperature dynamics indicated high connectivity between the streambed and the stream. Further downstream, streambed pore water geochemistry indicated ground water discharge occurring at the pool-riffle transition. Assessing streambed biogeochemical cycling may be facilitated by coupling streambed temperature measurements with pore water geochemistry and can aid in understanding how hyporheic exchange contributes to overall stream biogeochemistry.

Rapid exchange of stream water and groundwater in streambeds creates hotspots of biogeochemical cycling of redox-sensitive solutes. Although stream-groundwater interaction can be increased through stream restoration, there are few detailed studies of the increased heterogeneity of water and solute fluxes through the streambed and associated patterns of biogeochemical processes around stream restoration structures. In this study, we examined the seasonal patterns of water and solute fluxes through the streambed around a stream restoration structure to relate patterns of water flux through the streambed to morphology of the channel and biogeochemical processes occurring in the bed. We characterized different biogeochemical zones in the streambed using principal component analysis (PCA) and examined the change in spatial patterns of these zones during different seasons. The PCA results show that two principal components summarized 83% of the variance in the original data set. Streambed pore water was characterized as oxic (indicating production of nitrate), anoxic (indicating sulfate, iron and manganese reduction), or stream-like (indicating there was minimal change in the stream water chemistry in the bed). Regardless of season of the year, anoxic zones were predominantly located upstream of the structure, in a low-velocity pool, and oxic zones were predominantly located downstream of the structure, in a turbulent riffle. We expect structures that span the full channel, are impermeable, and permanent, such as those installed in natural channel design restoration will similarly impact biogeochemical processing in the streambed. The installation of these types of restoration structures may be a way to increase the degree of biogeochemical cycling in stream ecosystems.

Deleterious effects of urban stormwater are widely recognized. In several countries, regulations have been put into place to improve the conditions of receiving water bodies, but planning and engineering of stormwater control is typically carried out at smaller scales. Quantifying cumulative effectiveness of many stormwater control measures on a watershed scale is critical to understanding how small‐scale practices translate to urban river health. We review 100 empirical and modelling studies of stormwater management effectiveness at the watershed scale in diverse physiographic settings. Effects of networks with stormwater control measures (SCMs) that promote infiltration and harvest have been more intensively studied than have detention‐based SCM networks. Studies of peak flows and flow volumes are common, whereas baseflow, groundwater recharge, and evapotranspiration have received comparatively little attention. Export of nutrients and suspended sediments have been the primary water quality focus in the United States, whereas metals, particularly those associated with sediments, have received greater attention in Europe and Australia. Often, quantifying cumulative effects of stormwater management is complicated by needing to separate its signal from the signal of urbanization itself, innate watershed characteristics that lead to a range of hydrologic and water quality responses, and the varying functions of multiple types of SCMs. Biases in geographic distribution of study areas, and size and impervious surface cover of watersheds studied also limit our understanding of responses. We propose hysteretic trajectories for how watershed function responds to increasing imperviousness and stormwater management. Even where impervious area is treated with SCMs, watershed function may not be restored to its predevelopment condition because of the lack of treatment of all stormwater generated from impervious surfaces; non‐additive effects of individual SCMs; and persistence of urban effects beyond impervious surfaces. In most cases, pollutant load decreases largely result from run‐off reductions rather than lowered solute or particulate concentrations. Understanding interactions between natural and built landscapes, including stormwater management strategies, is critical for successfully managing detrimental impacts of stormwater at the watershed scale.

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Hennig Brandt's discovery of phosphorus (P) occurred during the early European colonization of the Chesapeake Bay region. Today, P, an essential nutrient on land and water alike, is one of the principal threats to the health of the bay. Despite widespread implementation of best management practices across the Chesapeake Bay watershed following the implementation in 2010 of a total maximum daily load (TMDL) to improve the health of the bay, P load reductions across the bay's 166,000‐km2 watershed have been uneven, and dissolved P loads have increased in a number of the bay's tributaries. As the midpoint of the 15‐yr TMDL process has now passed, some of the more stubborn sources of P must now be tackled. For nonpoint agricultural sources, strategies that not only address particulate P but also mitigate dissolved P losses are essential. Lingering concerns include legacy P stored in soils and reservoir sediments, mitigation of P in artificial drainage and stormwater from hotspots and converted farmland, manure management and animal heavy use areas, and critical source areas of P in agricultural landscapes. While opportunities exist to curtail transport of all forms of P, greater attention is required toward adapting P management to new hydrologic regimes and transport pathways imposed by climate change. Core Ideas At the midpoint of the Chesapeake TMDL, dissolved P is increasing in some tributaries. Lingering concerns include legacy P, artificial drainage, animal heavy use areas. Extreme events represent an acute risk to water quality.

Increasing specific conductance (SC) and chloride concentrations [Cl] negatively affect many stream ecosystems. We characterized spatial variability in SC, [Cl], and exceedances of Environmental Protection Agency [Cl] criteria using nearly 30 million high-frequency observations (2–15 min intervals) for SC and modeled [Cl] from 93 sites across three regions in the eastern United States: Southeast, Mid-Atlantic, and New England. SC and [Cl] increase substantially from south to north and within regions with impervious surface cover (ISC). In the Southeast, [Cl] weakly correlates with ISC, no [Cl] exceedances occur, and [Cl] concentrations are constant with time. In the Mid-Atlantic and New England, [Cl] and [Cl] exceedances strongly correlate with ISC. [Cl] criteria are frequently exceeded at sites with greater than 9–10% ISC and median [Cl] higher than 30–80 mg/L. Tens to hundreds of [Cl] exceedances observed annually at most of these sites help explain previous research where stream ecosystems showed changes at (primarily nonwinter) [Cl] as low as 30–40 mg/L. Mid-Atlantic chronic [Cl] exceedances occur primarily in December–March. In New England, exceedances are common in nonwinter months. [Cl] is increasing at nearly all Mid-Atlantic and New England sites with the largest increases at sites with higher [Cl].

Green stormwater infrastructure implementation in urban watersheds has outpaced our understanding of practice effectiveness on streamflow response to precipitation events. Long-term monitoring of experimental suburban watersheds in Clarksburg, Maryland, USA, provided an opportunity to examine changes in event-based streamflow metrics in two treatment watersheds that transitioned from agriculture to suburban development with a high density of infiltration-focused stormwater control measures (SCMs). Urban Treatment 1 has predominantly single family detached housing with 33% impervious cover and 126 SCMs. Urban Treatment 2 has a mix of single family detached and attached housing with 44% impervious cover and 219 SCMs.Differences in streamflow-event magnitude and timing were assessed using a beforeafter-control-reference-impact design to compare urban treatment watersheds with a forested control and an urban control with detention-focused SCMs. Streamflow and precipitation events were identified from 14 years of sub-daily monitoring data with an automated approach to characterize peak streamflow, runoff yield, runoff ratio, streamflow duration, time to peak, rise rate, and precipitation depth for each event.Results indicated that streamflow magnitude and timing were altered by urbanization

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