Abstract. Glycidyl esters of epoxidized fatty acids derived from soybean oil (EGS) and linseed oil (EGL) have been synthesized to have higher oxirane content, more reactivity and lower viscosity than epoxidized soybean oil (ESO) or epoxidized linseed oil (ELO). The EGS and ESO, for comparison, were used neat and in blends with diglycidyl ether of bisphenol A (DGEBA). Thermosetting resins were fabricated with the epoxy monomers and either BF 3 catalyst or anhydride. The curing behaviors, glass transition temperatures, crosslink densities and mechanical properties were tested. The results indicated that polymer glass transition temperatures were mostly a function of oxirane content with additional influence of glycidyl versus internal oxirane reactivity, pendant chain content, and chemical structure and presence of saturated components. EGS provided better compatibility with DGEBA, improved intermolecular crosslinking and glass transition temperature, and yielded mechanically stronger polymerized materials than materials obtained using ESO. Other benefits of the EGS resin blend systems were significantly reduced viscosities compared to either DGEBA or ESO-blended DGEBA counterparts. Therefore, EGS that is derived from renewable sources has improved potential for fabrication of structural and structurally complex epoxy composites, e.g., by vacuum-assisted resin transfer molding.
Moisture in polymerization of a cationically cured silicone epoxy monomer blend is an important parameter that affects the resulting polymer properties. We report the kinetics of the cationic polymerization of epoxy monomers as a function of water concentration, directly quantified using Karl Fischer (KF) titration that was characterized using Fourier transform infrared (FTIR) spectroscopy and also the mechanical strength of resulting polymers via diametral tensile strength measurements. Methodology and results for a silicone epoxy monomer material were compared with the same methodology applied to a "control" monomer, 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexyane carboxylate, for which moisture effects have been previously studied. Initially, an increase in moisture during cationic polymerization of epoxy caused increased rate (ROC) and degree of conversion (DOC) that for the silicone epoxy was followed by decreased DOCs for water contents approaching saturation, i.e., [H 2 O]0.19 wt %. Further, the rate of conversion was also affected by the presence of moisture with a trend analogous to the DOC. Diametral tensile strength measurements found that small amounts of water present during polymerization caused small changes in tensile strength but found polymer strengths to be significantly decreased if initial water concentrations approached saturation or were in excess of saturation. Lower strengths corresponded with reduced rates of conversion and DOCs.
Polymers based on vegetable oils (VOs) have the potential to replace or augment traditional, petroleum-based polymers. Epoxidized vegetable oils (EVOs) are a form of epoxy monomer derived from raw VOs. They are widely used as plasticizers and intermediates for polyols of bio-based polyurethane or unsaturated polyesters. A comprehensive review in this chapter covers epoxy thermoset polymers prepared from EVOs and analogous, fatty-acid-derived epoxy monomers resins. The scope, performance, and limitations with respect to utilization of such materials in various applications are highlighted. The utility of EVO monomers is enabled or limited by their reactivity and by the physical properties of their resulting polymers. The effects of the chemical structures of VO-based epoxy, various catalysts, and co-monomers on the properties of thermoset polymers are especially emphasized.
In this research, the non-linear dynamics of the drill string system model, considering the influence of fluid—structure coupling and the effect of support stiffness, are investigated. Using Galerkin’s method, the equation of motion is discretized into a second-order differential equation. On the basis of an improved mathematical model, numerical simulation is carried out using the Runge—Kutta integration method. The effects of parameters, such as forcing frequency, perturbation amplitude, mass ratio and flow velocity, on the dynamic characteristics of the drill string system are studied under different support stiffness coefficients, in which bifurcation diagrams, waveforms, phase diagrams and Poincaré maps of the system are provided. The results indicate that there are various dynamic model behaviors for different parameter excitations, such as periodic, quasi-periodic, chaotic motion and jump discontinuity. The system changes from chaotic motion to periodic motion through inverse period-doubling bifurcation, and the support stiffness has a significant influence on the dynamic response of the drill string system. Through in-depth study of this problem, the dynamic characteristics of the drill string can be better understood theoretically, so as to provide a necessary theoretical reference for prevention measures and a reduction in the number of drilling accidents, while facilitating the optimization of the drilling process, and provide basis for understanding the rich and complex nonlinear dynamic characteristics of the deep-hole drill string system. The study can provide further understanding of the vibration characteristics of the drill string system.
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