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Burying beetles of the genus Nicrophorus localize small vertebrate carcasses by emitted volatiles. The carcass that serves as reproduction and breeding site is buried in the soil by the beetles. Biparental care for offspring includes both preservation of the carrion and its preparation as diet and nursery. Buried carcasses show no signs of microbial decay, and those experimentally treated with Nicrophorus secretions are known to grow fewer bacteria and fungi. In order to investigate the chemical composition of these secretions, we used GC-MS for analysis of methanolic extracts of anal and oral secretions released by adult N. vespilloides. Furthermore, we analyzed the headspace of adult N. vespilloides by SPME-GC-MS and searched for compounds with known antimicrobial activity. We identified 34 compounds in the headspace, and anal and oral secretions, 26 of which occurred consistently. We discuss the ecological relevance of these compounds with respect to both their antimicrobial activity and ecological relevance.

Nonylphenol (NP) as an intermediate from anaerobic degradation of widely used nonionic surfactants occurs widespread in the environment. Partition behavior of this toxic and endocrine-disrupting chemical between soil and water was not examined until yet. The objective of this investigation was to quantify sorption and desorption behavior of 4-nonyl[14C]phenol in a set of 51 soils using the batch equilibrium approach. Kinetic studies indicated apparent equilibrium within 20 h. Sorption was influenced by sorbate structure as could be shown with branched 4-nonyl[14C]phenol and the linear 4-n-NP, respectively. Linear 4-n-NP behaves differently from the branched isomers of 4-NP. Sorption of 4-nonyl[14C]phenol tested with five different initial concentrations resulted in linearly fitted isotherms that provided calculation of sorption partition coefficients (KP). Desorption partition coefficients (KP-des) revealed hysteresis independent of soil properties but decreasing with decreasing initial NP concentrations. KP values were correlated with organic carbon content of the soils yielding a log KOC of 3.97.

Generation of organic waste is increasing worldwide and strategies for its environmentally sound use must be developed and optimized. Regulations in European countries and the USA differ largely with respect to requirements of organic waste quality and the quantities of pollutants which can be added to the soil. Research has shown beneficial effects regarding the improvement of soil fertility. Enrichment of total metals in soil was attributed to long‐term sludge application but the effect on bioavailability of metals must be further clarified. A number of organic pollutants, such as hydrophobic persistent organic contaminants and surfactants, are known to accumulate in organic wastes. However, the former interact strongly with organic matter in the sludge‐soil‐plant system and systemic plant uptake is generally assumed to be minimal. Surfactants may cause adverse environmental impacts when they enter sewage systems in high loads and accumulate in sludge. Surfactants and some of their metabolites are not readily biodegraded in non‐aerated environments. Due to their toxicity and estrogenic activity, of nonylphenol for example, more research is needed to optimize analytical techniques and to trace their behavior in soil. Some options to cope with the risks of huge amounts of organic waste and also some benefits are presented: (1) further limitation of standards for pollutants and reduced application rates; (2) improved treatment of sewage sludge to reduce the total and bioavailable portions of both heavy metals and organic pollutants; (3) adaptation of waste application rates to soil properties such as sorption capacity for pollutants; (4) harmonization of analytical protocols for organic contaminants, i.e. surfactants and metabolites, enabling a more thorough monitoring of the wastes which are to be applied onto soils.

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An analysis method for aqueous samples by the direct combination of C18/SCX mixed mode thin-film microextraction (TFME) and desorption electrospray ionization mass spectrometry (DESI-MS) was developed. Both techniques make analytical workflow simpler and faster, hence the combination of the two techniques enables considerably shorter analysis time compared to the traditional liquid chromatography mass spectrometry (LC-MS) approach. The method was characterized using carbamazepine and triclosan as typical examples for pharmaceuticals and personal care product (PPCP) components which draw increasing attention as wastewater-derived environmental contaminants. Both model compounds were successfully detected in real wastewater samples and their concentrations determined using external calibration with isotope labeled standards. Effects of temperature, agitation, sample volume, and exposure time were investigated in the case of spiked aqueous samples. Results were compared to those of parallel HPLC-MS determinations and good agreement was found through a three orders of magnitude wide concentration range. Serious matrix effects were observed in treated wastewater, but lower limits of detection were still found to be in the low ng L(-1) range. Using an Orbitrap mass spectrometer, the technique was found to be ideal for screening purposes and led to the detection of various different PPCP components in wastewater treatment plant effluents, including beta-blockers, nonsteroidal anti-inflammatory drugs, and UV filters.

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