Nozzle clogging in continuous casting of steel originates by the adherence of alumina particles and other oxides, precipitated during the liquid steel deoxidation, on the refractory material’s surface. Hence, these particles’ nucleation and growth rates in supersaturated melts are analyzed considering, specifically, the role of the interfacial tensions between alumina, silica, and other oxides and the liquid metal. Weak steel deoxidizers like silicon do not need high supersaturations favoring high nucleation rates, giving particles’ narrow size distributions thanks to fast diffusion and Ostwald-ripening coagulation. Strong deoxidizers, like aluminum, need high supersaturation levels leading to broad size distributions. Besides, the morphology of these particles depends on the nucleation and growth mechanisms. The adhesion forces among the deoxidation particles, forming clusters, depending on the morphology and the oxide’s chemistry. The stability of the nozzle’s clog, adhered to the nozzle’s wall, depends on the interface tensions between the melt and the nozzle’s refractory surface and between the melt and the inclusion. The results obtained here help set up basic recommendations in steel refining and materials specifications of casting nozzles.
Molten steel is alloyed during tapping from the melting furnace to the argon-bottom stirred ladle. The metallic additions thrown to the ladle during the ladle filling time are at room temperature. The melting rates or kinetics of sinking-metals, like nickel, are simulated through a multiphase Euler–Lagrangian mathematical model during this operation. The melting rate of a metallic particle depends on its trajectory within regions of the melt with high or low turbulence levels, delaying or speeding up their melting process. At low steel levels in the ladle, the melting rates are higher on the opposite side of the plume zone induced by the bottom gas stirring. This effect is due to its deviation after the impact of the impinging jet on the ladle bottom. The higher melting kinetics are located on both sides at high steel levels due to the more extensive recirculation flows formed in taller baths. Making the additions above the eye of the argon plume spout increases the melting rate of nickel particles. The increase of the superheat makes the heat flux more significant from the melt to the particle, increasing its melting rate. At higher superheats, the melting kinetics become less dependent on the fluid dynamics of the melt.
ResumenUtilizando las técnicas de modelación física y matemática, se estudia en detalle el comportamiento del flujo de acero líquido en una artesa de salidas múltiples para colar tochos (bloonís). Se estudiaron tres casos: una artesa sin accesorios (SA), una artesa con dos pares de bafles y una placa de impacto ondulada (BPIO)^ y una artesa equipada con un inhibidor de turbulencia y un par de represas (Uarn^) (IT&D). También, se simuló matemáticamente la difusión turbulenta de la mezcla química del trazador y se comparó con los resultados experimentales. La configuración IT&D mostró una buena distribución del trazador entre las salidas y una mejora en las características del patrón de flujo reduciendo el retroflujo, logrando una buena relación de volumen mezclado y de flujo tapón. El modelo de transferencia de masa, acoplado con el modelo de turbulencia''^ k-sf predice aceptablemente bien la mezcla química experimental del trazador en el modelo físico.Palabras clave Metalurgia de la artesa. Modelos físicos y matemáticos. Control del flujo de acero. Dispersión del trazador. Inhibidores de turbulencia.Flow control of molten steel in a multi-strand continuous casting tundish Abstract Keywords
Slab molds receive liquid steel from the tundish through bifurcated submerged entry nozzles (SEN) using a slide valve as throughput control. Due to the off-centering position of the three plates’ orifices that conform to the valve to control the steel passage, the flow inside the nozzle and mold is inherently biased toward the valve opening side. In the practical casting, a biased flow induces inhomogeneous heat fluxes through the mold copper plates. The nozzle design itself is also a challenge, and has direct consequences on the quality of the product. A diagnosis of the casting process regarding the internal and external flows, performed through experimental and mathematical simulation tools, made it possible to reach concrete results. The mathematical simulations predicted the flow dynamics, and the topography and levels variations of the meniscus characterized through a full-scale water model. The flows are biased, and the meniscus level fluctuations indicated that the current nozzle is not reliable to cast at the two extremes of the casting speeds of 0.9 m/min and 1.65 m/min, due to the danger of mold flux entrainment. A redesign of the nozzle is recommended, based on the experimental and mathematical results presented here.
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