The turbulent phenomena occurring in the thin slab mold affect the final product quality. Therefore, it is essential to carry out studies to understand and control their occurrence. Current research aims to study the electromagnetic brake (EMBr) effects on the flow patterns in a funnel thin slab mold. The objective is to prevent the detrimental phenomenon known as dynamic distortions (DD) of the flow, applying the EMBr in the typical horizontal position (H-EMBr) and a new vertical position close to the narrow faces (V-EMBr). The fluid dynamics are simulated using the Reynolds stress model (RSM), the Volume of Fluid (VOF) model and the Maxwell equations in their magnetohydrodynamics (MHD) simplification. The results show that the H-EMBr effectively counteracts the DD phenomenon by reducing the submerged entry nozzle (SEN) ports' mass flow rate differences. The EMBr reduces the highest meniscus fluctuations from −10 to ±3 mm with a field intensity of 0.1T and almost 0 mm for higher field intensities. In contrast, the V-EMBr configuration does not reduce or control at all the DD phenomenon, even though eliminating the upper roll flows does not diminish the meniscus fluctuation amplitudes and induces new small roll flows close to the SEN's wall.
Three-phase interactions (metal-slag-argon) in ladle stirring operations have strong effects on the metal-slag mass transfer processes. Specifically, the thickness of the slag controls the fluid turbulence to an extent that once trespassing a critical thickness, increases of stirring strength no longer effect the flow. To analyze these conditions, a physical model considering the three phases was built to study liquid turbulence in the proximities of the metal-slag interface. A velocity probe placed close to the interface permitted the continuous monitoring and statistical analyses of any turbulence. The slag eye opening was found to be strongly dependent on the stirring conditions, and the mixing times decreased with thin slag thicknesses. Slag entrainment was enhanced with thick slag layers and high flow rates of the gas phase. A multiphase model was developed to simulate these results and was found to be a good agreement between experimental and numerical results.
The characterization of the fluid flow of liquid steel in a slab mold, using two nozzle designs under unclogged and clogged conditions, is performed using physical and mathematical simulations. Nozzle A, with an expanding and contracting geometry, yields larger sub-meniscus experimental velocities than nozzle B, with internal flow deflectors. The numerical predictions indicate quick time-changing velocity profiles in the submeniscus region between the mold’s narrow face and the nozzles. The flow deflectors in nozzle B have two effects; the high dissipation rate of kinetic energy in the upper-half length induces lower velocities in the ports than nozzle A. The neutralization of the biased flow caused by the sliding gate allows a balanced fluid through the ports. According to the results, nozzle A yields velocity profiles in the sub-meniscus region with larger standard deviations than nozzle B, leading to an unstable bath surface. The clogged nozzles produced biased-asymmetrical flow patterns in the mold, finding approximated matchings between numerical predictions and experimental measurements. The internal protrusions of the deposits lead to covariance losses of the bath surface wave heights. The use of internal deflectors helped to decrease the amount of clog material in nozzle B.
Carbides are used extensively as cutting tools, forming dies, and recently in catalysis applications, among other industrial applications. In this work, the synthesis and characterization of a nanostructured MoW bimetallic carbide were carried out by mechanical alloying with a mixture of elemental powders with a nominal composition of W1.5Mo6C2.5 at different grinding times as follows: 25, 50, and 75 h in a low-energy ball mill at a speed of 500 rpm and 125 and 150 h in a high-energy ball mill at a speed of 1500 rpm. The formation of a solid solution was observed at 150 h of milling; the nanostructured bcc MoW carbide corresponded to the main phase in the sample, besides the presence of the nanostructured MoW alloy as a secondary phase with an average crystal size of 40.8 nm. The phases and morphology at every stage of milling were studied by: X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and Vickers hardness. As the milling time increased, the hardness of these particles increased from 10.5 to 31.48 GPa for the powder particles milled for 150 h. The samples obtained at 125 and 150 h of milling were evaluated during catalytic aqua-thermolysis of heavy oil to analyze fuel desulfurization properties by Fourier transform infrared (FTIR) techniques. The results showed the breaking of S-S bonds, indicating the existence of a desulfurization reaction of heavy oil.
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