Aligned CNT nanocomposites with variable volume fraction, up to 20%, are demonstrated. Biaxial mechanical densification of aligned CNT forests, followed by capillarity-driven wetting using unmodified aerospace-grade polymers, creates centimeter-scale specimens. Characterizations confirm CNT alignment and dispersion in the thermosets, providing a useful platform for controlled nanoscale interaction and nanocomposite property studies that emphasize anisotropy.
Recent advances in fabricating controlled-morphology vertically aligned carbon nanotubes (VA-CNTs) with ultrahigh volume fraction create unique opportunities for markedly improving the electromechanical performance of ionic polymer conductor network composite (IPCNC) actuators. Continuous paths through inter-VA-CNT channels allow fast ion transport, and high electrical conduction of the aligned CNTs in the composite electrodes lead to fast device actuation speed (>10% strain/second). One critical issue in developing advanced actuator materials is how to suppress the strain that does not contribute to the actuation (unwanted strain) thereby reducing actuation efficiency. Here our experiments demonstrate that the VA-CNTs give an anisotropic elastic response in the composite electrodes, which suppresses the unwanted strain and markedly enhances the actuation strain (>8% strain under 4 volts). The results reported here suggest pathways for optimizing the electrode morphology in IPCNCs using ultra-high volume fraction VA-CNTs to further enhanced performance.
Analytical models are presented for the Mode I interlaminar fracture of laminated composites reinforced with aligned carbon nanotubes (CNTs). The models are based on the crack-closure technique for fiber bridging, where the aligned CNTs enhance toughness mechanistically through either pullout (frictional sliding) from the matrix or sword-in-sheath sliding. The models are independent of the scale of reinforcement and demonstrate significant enhanced toughening for nanoscale reinforcement (CNTs) as opposed to typical mm-scale reinforcements (stitches and Z-pins). Complete analytical expressions for crack-growth resistance (GR(Δa)) are obtained including normalized closed-form expressions for steady-state toughness for any scale of z-direction fiber reinforcement. The model is verified by comparison to previous experimental results for Z-pins and also aligned CNTs, and is used to define regimes where the competing mechanisms of toughening are operative. CNT strength is a key parameter limiting toughness enhancement in the frictional pullout mechanism.
Since 2012 there has been a rapid rise in the development of triboelectric nanogenerators due to their potential applications in the field of energy harvesting and self-powered sensors for vibrations, accelerations, touches, pressures and other mechanical motions. This study suggests a novel triboelectric nanogenerator based on the interaction between polyvinylidene fluoride and polyvinylpyrrolidone submicron fibers. Polyvinylpyrrolidone is introduced as a new material for the TENG because of its tendency of losing electrons easily, while polyvinylidene fluoride is selected for its strongelectron attracting ability. Electrospinning is suggested as a fabrication method for the nanofibers due to its simplicity, versatility and low-cost. Furthermore, the paper explores the possibility to use this triboelectric nanogenerator as a self-powered pressure sensor. For this purpose, the nanogenerator is subjected to dynamic mechanic analysis which produces controlled pressure forces applied with a certain frequency. This is the first work to suggest the use of dynamic mechanical analyzer to study the relation between the applied mechanical stimulus and the electric responses of the triboelectric nanogenerator. Eventually the sensitivity of the nanogenerator to different pressures is analysed. A directly proportional relationship is found between the pressure applied and the resultant voltage and current amplitudes. The developed nanogenerator reacts to pressure in real time and as a sensor it exhibits a very high sensitivity and low experimental error for repeated measurements. The main contributions of this study are the development of a novel nanogenerator based on the triboelectric effect between polyvinylidene fluoride and polyvinylpyrrolidone electrospun fibers and the investigation for its potential use as a selfpower pressure sensor. Eventually, the paper explores the advantages of dynamic mechanical analyzer for pressure analysis.
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