The present work studies the possibility of energy recovery by thermal conversion of combustible residual materials, namely tires and rubber-plastic, plastic waste from outdoor luminaires. The waste has great potential for energy recovery (HHV: 38.6 MJ/kg for tires and 31.6 MJ/kg for plastic). Considering the thermal conversion difficulties of these residues, four co-combustion tests with mixtures of tires/plastics + pelletized Miscanthus, and an additional test with 100% Miscanthus were performed. The temperature was increased to the maximum allowed by the equipment, about 500 °C. The water temperature at the boiler outlet and the water flow were controlled (60 °C and 11 L/min). Different mixtures of residues (0–60% tires/plastics) were tested and compared in terms of power and gaseous emissions. Results indicate that energy production increased with the increase of tire residue in the mixture, reaching a maximum of 157 kW for 40% of miscanthus and 60% of tires. However, the automatic feeding difficulties of the boiler also increased, requiring constant operator intervention. As for plastic and rubber waste, fuel consumption generally decreased with increasing percentages of these materials in the blend, with temperatures ranging from 383 °C to 411 °C. Power also decreased by including such wastes (66–100 kW) due to feeding difficulties and cinder-fusing problems related to ash melting. From the study, it can be concluded that co-combustion is a suitable technology for the recovery of waste tires, but operational problems arise with high levels of residues in the mixture. Increasing pollutant emissions and the need for pre-treatments are other limiting factors. In this sense, the thermal gasification process was tested with the same residues and the same percentages of mixtures used in the co-combustion tests. The gasification tests were performed in a downdraft reactor at temperatures above 800 °C. Each test started with 100% acacia chip for reference (like the previous miscanthus), and then with mixtures of 0–60% of tires and blends of plastics and rubbers. Results obtained for the two residues demonstrated the viability of the technology, however, with mixtures higher than 40% it was very difficult to develop a process under stable conditions. The optimum condition for producing a synthesis gas with a substantial heating value occurred with mixtures of 20% of polymeric wastes, which resulted in gases with a calorific value of 3.64 MJ/Nm3 for tires and 3.09 MJ/Nm3 for plastics and rubbers.

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The recovery of urban waste is a social demand and a measure of the energy-environmental sustainability of cities and regions. In particular, waste of electrical origin, waste of electrical and electronic materials (WEEE) can be recovered with great success. The plastic fraction of these wastes allows their gasification mixed with biomass, and the results allow for producing syngas with a higher energy potential. This work allows for obtaining energy from the recovery of obsolete materials through thermochemical conversion processes of the plastic waste from the disassembly of the luminaires by mixing the said plastic waste in different proportions with the biomass of crop residues (olive). The gasification tests of these mixtures were carried out in a downstream fixed-bed drown daft reactor, at temperatures of approximately 800 °C. The results demonstrate the applied technical and economic feasibility of the technology by thermal gasification, for the production of LHV (Low Heating Value) syngas with highest power energy (more than 5 MJ/m3) produced in mixtures of up to 20% of plastic waste. This study was complemented with the economic-financial analysis. This research can be used as a case study for the energy recovery through gasification processes of plastic waste from luminaires (WEEE), mixed with agricultural biomass that is planned to be carried out on a large scale in the Alentejo (Portugal), as a solution applied in circular economy strategies.

The present study evaluates the digestion of cork boiling wastewater (CBW) through a biochemical methane potential (BMP) test. BMP assays were carried out with a working volume of 600 mL at a constant mesophilic temperature (35 °C). The experiment bottles contained CBW and inoculum (digested sludge from a wastewater treatment plant (WWTP)), with a ratio of inoculum/substrate (Ino/CBW) of 1:1 and 2:1 on the basis of volatile solids (VSs); the codigestion with food waste (FW) had a ratio of 2/0.7:0.3 (Ino/CBW:FW) and the codigestion with cow manure (CM) had a ratio of 2/0.5:0.5 (Ino/CBW:CM). Biogas and methane production was proportional to the inoculum substrate ratio (ISR) used. BMP tests have proved to be valuable for inferring the adequacy of anaerobic digestion to treat wastewater from the cork industry. The results indicate that the biomethane potential of CBWs for Ino/CBW ratios 1:1 and 2:1 is very low compared to other organic substrates. For the codigestion tests, the test with the Ino/CBW:CM ratio of 2/0.7:0.3 showed better biomethane yields, being in the expected values. This demonstrated that it is possible to perform the anaerobic digestion (AD) of CBW using a cosubstrate to increase biogas production and biomethane and to improve the quality of the final digestate.

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The behavior of chars from the carbonization process were studied when the lignocellulosic biomass was incorporated into the waste of electrical and electronic equipment for chlorine removal. Tests were performed at 300°C with a heating rate of 15°C/min and residence time of 60 min. Compositions studied had 100, 75, 50, 25 and 0% of waste electrical and electronic equipment (WEEE) in the mixtures. The composition of 50% WEEE with 50% lignocellulosic biomass presented the best char properties, having an increment of the calorific value in 5.5% relative to the initial value, and chlorine removal of 23.4% when compared to the forestry biomass.

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The recovery of noble metals from electrical wires and cables results in waste materials such as polyvinyl chloride (PVC) and polyethylene (PE), that is, waste insulation electrical cables (WIEC), which have been processed by gasification for energy recovery. This study focused on the effect of blending the ratio of WIEC on the gasification feedstock composition and the lower heating value (LHV) of produced syngas, through controlled tests and tests under different loads on the generator. The controlled gasification experiments were carried out at blending ratios between pine biomass and WIEC of 90:10, 80:20, and 70:30 and with pine biomass only (100%). For the loads gasification, the experiments were carried out at a blending ratio of 80:20. The controlled experimental results presented that the highest hydrogen content, approximated 17.7 vol.%, was observed at a blending ratio of 70:30 between pine biomass and WIEC and the highest LHV of syngas was observed at a blending ratio of 90:10, with 5.7 MJ/Nm3. For the load gasification experiments, the results showed that the highest hydrogen content was obtained with a load of 15 kW in the generator, approximately 18.48 vol.% of hydrogen content, and the highest LHV of synthesis gas was observed during the 5 kW test, with 5.22 MJ/Nm3. Overall, the new processing of waste insulation electrical cables using a downdraft gasification reactor demonstrates great promise for high quality syngas production.