We have found that the addition of low concentrations of certain inexpensive light cosolvents to alkaline/polymer (AP) solutions dramatically improves the performance of AP corefloods in two important ways. First, the addition of cosolvent promotes the formation of low-viscosity microemulsions rather than viscous macroemulsions. Second, these light cosolvents greatly improve the phase behavior in a way that can be tailored to a particular oil, temperature, and salinity. This new chemical enhanced-oil-recovery (EOR) technology uses polymer for mobility control and has been termed alkali/cosolvent/polymer (ACP) flooding. ACP corefloods perform as well as alkaline/surfactant/polymer (ASP) corefloods while being simpler and more robust. We report 12 successful ACP corefloods using four different crude oils ranging from 12 to 24 API. The ACP process shows special promise for heavy oils, which tend to have large fractions of soap-forming acidic components, but is applicable across a wide range of oil gravity.
Kuwait Oil Company has recognized the implications of the recent technological advances that are very likely to transform the oil industry and make chemical enhanced oil recovery methods such as alkaline-surfactant-polymer (ASP) flooding a hallmark of enhanced oil recovery. An ambitious program to apply chemical EOR to both sandstone and carbonate oil reservoirs in Kuwait is already underway. In this paper, we present the first field results of this effort. First we discuss the approach used to design a novel surfactant formulation for a high-salinity, high-temperature, highly heterogeneous carbonate reservoir, the Sabriyah-Mauddud in Kuwait, and the evaluation of the ASP process in three one-spot ASP pilots (i.e., three two-stage single well chemical tracer tests). We summarize the results of the surfactant laboratory experiments used to select the final ASP formulation and we present detailed results and interpretation of the subsequent single-well chemical tracer test (SWCTTs) results using ASP chemicals as well as details of the field operation including quality control measurements performed in the field lab. The residual oil saturations measured before and after the injection of the ASP slug and polymer drives clearly show that the chemical solution was effective in mobilizing and displacing residual oil saturation following injection of water. The injectivity of high molecular weight polyacrylamide polymer was excellent despite the low permeability of the formation.
Summary A hybrid process is developed and optimized for heavy-oil recovery that combines moderate reservoir heating and chemical enhanced oil recovery in the form of alkali/cosolvent/polymer flood. The process is simulated by use of a model derived from existing laboratory and pilot data of a 5,000-cp heavy-oil field. It is found that hot waterflooding is efficient in heating the reservoir only when high early injectivity is achievable. This may not be the case if incipient fluid injectivity is low and/or long, continuous, horizontal shale baffles are present. To remedy the former, an electrical-preheating period is devised, whereas switching to a horizontal flood could overcome the latter. Once the reservoir temperature is raised sufficiently, a moderately unstable alkali/cosolvent/polymer flood is capable of mobilizing and displacing oil. A best combined strategy for efficient reservoir heating, high oil recovery, and cost effectiveness is found to involve reducing the oil viscosity to values of approximately 300–500 cp and combining a degree of mobility control and low interfacial tension as recovery mechanisms.
We have found that the addition of low concentrations of certain inexpensive light co-solvents to alkaline-polymer solutions dramatically improves the performance of alkaline-polymer (AP) corefloods in two important ways. Firstly, addition of cosolvent promotes the formation of low viscosity microemulsions rather than viscous macroemulsions. Secondly, these light co-solvents greatly improve the phase behavior in a way that can be tailored to a particular oil, temperature and salinity. This new chemical EOR technology uses polymer for mobility control and has been termed Alkali-Co-solvent-Polymer (ACP) flooding. ACP corefloods perform as well as ASP corefloods while being simpler and more robust. We report 12 successful ACP corefloods using four different crude oils ranging from 12 to 24 °API. The ACP process shows special promise for heavy oils, which tend to have large fractions of soap-forming acidic components, but is applicable across a wide range of oil gravity.
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