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The Internet of things (IoT) is still in its infancy and has attracted much interest in many industrial sectors including medical fields, logistics tracking, smart cities and automobiles. However as a paradigm, it is susceptible to a range of significant intrusion threats. This paper presents a threat analysis of the IoT and uses an Artificial Neural Network (ANN) to combat these threats. A multi-level perceptron, a type of supervised ANN, is trained using internet packet traces, then is assessed on its ability to thwart Distributed Denial of Service (DDoS/DoS) attacks. This paper focuses on the classification of normal and threat patterns on an IoT Network. The ANN procedure is validated against a simulated IoT network. The experimental results demonstrate 99.4% accuracy and can successfully detect various DDoS/DoS attacks.

Interest in the chemistry of ferrocene remains intense, largely due to applications within catalysis. New synthetic routes to unsymmetrical ferrocene ligands have provided another facet to this area, as substituents can be designed to be electronically- and/or sterically-distinct in order to affect the environment around the catalytically-active metal centre. This critical review provides a concise summary of the synthetic routes that have been applied to the synthesis of unsymmetrical ferrocene ligands, along with a systematic survey of the applications of these ligands in homogeneous catalysis. The aim is to help the reader select a suitable ferrocenediyl ligand for a particular synthetic application, and in the synthesis of ligands that require particular structural and/or electronic features.

As the world moves towards being increasingly dependent on computers and automation, building secure applications, systems and networks are some of the main challenges faced in the current decade. The number of threats that individuals and businesses face is rising exponentially due to the increasing complexity of networks and services of modern networks. To alleviate the impact of these threats, researchers have proposed numerous solutions for anomaly detection; however, current tools often fail to adapt to ever-changing architectures, associated threats and zero-day attacks. This manuscript aims to pinpoint research gaps and shortcomings of current datasets, their impact on building Network Intrusion Detection Systems (NIDS) and the growing number of sophisticated threats. To this end, this manuscript provides researchers with two key pieces of information; a survey of prominent datasets, analyzing their use and impact on the development of the past decade's Intrusion Detection Systems (IDS) and a taxonomy of network threats and associated tools to carry out these attacks. The manuscript highlights that current IDS research covers only 33.3% of our threat taxonomy. Current datasets demonstrate a clear lack of realnetwork threats, attack representation and include a large number of deprecated threats, which together limit the detection accuracy of current machine learning IDS approaches. The unique combination of the taxonomy and the analysis of the datasets provided in this manuscript aims to improve the creation of datasets and the collection of real-world data. As a result, this will improve the efficiency of the next generation IDS and reflect network threats more accurately within new datasets.

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Machine Learning (ML) and Deep Learning (DL) have been used for building Intrusion Detection Systems (IDS). The increase in both the number and sheer variety of new cyber-attacks poses a tremendous challenge for IDS solutions that rely on a database of historical attack signatures. Therefore, the industrial pull for robust IDSs that are capable of flagging zero-day attacks is growing. Current outlier-based zero-day detection research suffers from high false-negative rates, thus limiting their practical use and performance. This paper proposes an autoencoder implementation for detecting zero-day attacks. The aim is to build an IDS model with high recall while keeping the miss rate (false-negatives) to an acceptable minimum. Two well-known IDS datasets are used for evaluation—CICIDS2017 and NSL-KDD. In order to demonstrate the efficacy of our model, we compare its results against a One-Class Support Vector Machine (SVM). The manuscript highlights the performance of a One-Class SVM when zero-day attacks are distinctive from normal behaviour. The proposed model benefits greatly from autoencoders encoding-decoding capabilities. The results show that autoencoders are well-suited at detecting complex zero-day attacks. The results demonstrate a zero-day detection accuracy of 89–99% for the NSL-KDD dataset and 75–98% for the CICIDS2017 dataset. Finally, the paper outlines the observed trade-off between recall and fallout.

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A wireless sensor network (WSN) with the potential to monitor and locate partial discharge (PD) in high-voltage electricity substations using only received signal strength (RSS) is proposed. The advantages of an RSS-based operating principle over more traditional methods (e.g., time-of-arrival and time-difference-of-arrival) are described. Laboratory measurements of PD that emulate the operation of a PD WSN are presented. The hardware architecture of a prototype PD WSN is described and the particular challenges of an RSS-based location approach in an environment with an unknown, and spatially varying, path-loss index are discussed. It is concluded that an RSS-based PD WSN is a plausible solution for the monitoring of insulation integrity in electricity substations.