respectively. Because the experimental values of h( 7' ) are in good accord with those calculated, we consider that kN = 0 holds in the temperature range studied, as assumed above. It, therefore, is likely that the photoexcited CICr"I(TPP)Ac is fated to undergo the dissociation of the axial acetone or result in the formation of the 'TI state.When the 'TI state is formed, the 6T1 state is populated, leading to establishment of Boltzmann equilibrium between the 'TI and (RIKEN) for helpful discussions throughout this work.
The
complex
[(η5-C5H5)2TiB6H9]2
is prepared through the reaction of K[B6H9]
with
(η5-C5H5)2TiCl
in THF. It is a member of a small class of metalloboranes which
are edge-bonded derivatives of B6H10. The
compound is a paramagnetic dimer,
[(η5-C5H5)2TiB6H9]2.
The Ti(III) atom is formally a 17-electron species as
supported by ESR spectra. There is no evidence for Ti−Ti
interaction. The proposed structure resembles that of
[{(Ph2Me)3P}2PtB6H9]2.
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