Douglas L. Denton scite author profile

The complex [(η5-C5H5)2TiB6H9]2 is prepared through the reaction of K[B6H9] with (η5-C5H5)2TiCl in THF. It is a member of a small class of metalloboranes which are edge-bonded derivatives of B6H10. The compound is a paramagnetic dimer, [(η5-C5H5)2TiB6H9]2. The Ti(III) atom is formally a 17-electron species as supported by ESR spectra. There is no evidence for Ti−Ti interaction. The proposed structure resembles that of [{(Ph2Me)3P}2PtB6H9]2.

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Borane Addition Compounds of Bases

Moore

White

Kelly

et al. 1970

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Preparation and nuclear magnetic resonance studies of stereochemically nonrigid magnesium, zinc, and cadmium derivatives of hexaborane(10). Crystal and molecular structure of bis(tetrahydrofuran)magnesium bis(nonahydrohexaborate)

Denton¹,

Clayton²,

Mangion³

et al. 1976

Inorg. Chem.

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Douglas L. Denton

Mechanical Properties Characterization of an SMC-R50 Composite

Boron-nitrogen chemistry—II. Poly(aminoborane) [1]

Preparation of [(η⁵-C₅H₅)₂TiB₆H₉]₂: A Metallo Derivative of Hexaborane(10)

Borane Addition Compounds of Bases

Preparation and nuclear magnetic resonance studies of stereochemically nonrigid magnesium, zinc, and cadmium derivatives of hexaborane(10). Crystal and molecular structure of bis(tetrahydrofuran)magnesium bis(nonahydrohexaborate)

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Douglas L. Denton

Mechanical Properties Characterization of an SMC-R50 Composite

Boron-nitrogen chemistry—II. Poly(aminoborane) [1]

Preparation of [(η5-C5H5)2TiB6H9]2: A Metallo Derivative of Hexaborane(10)

Borane Addition Compounds of Bases

Preparation and nuclear magnetic resonance studies of stereochemically nonrigid magnesium, zinc, and cadmium derivatives of hexaborane(10). Crystal and molecular structure of bis(tetrahydrofuran)magnesium bis(nonahydrohexaborate)

Contact Info

Product

Resources

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Preparation of [(η⁵-C₅H₅)₂TiB₆H₉]₂: A Metallo Derivative of Hexaborane(10)