Pyrolysis of tobacco waste can provide an effective management option, as it produces biogas and bio-oils, which can be subsequently applied for energy recovery, and biochar, which can be used for carbon sequestration when stored in soils. This work assesses the pyrolysis behavior of tobacco waste and reveals four stage pyrolysis mechanism consisting of dehydration (<200 °C), torrefaction (≈300 °C), charring (≈500 °C), and carbonization (≈750 °C). The calorific value of the evolved biogas products at the charring temperature of 500 °C was estimated to be reasonably high and the products can be combusted to generate energy required to self-sustain the pyrolysis process. The bio-oils contained complex chemical structure consisting of nicotine, phenols, and organic acids. The biochar product exhibited enrichment in the fixed carbon, ash, and nutrients P and K, while N remained at relatively constant concentration throughout the pyrolysis process.
The objective of the work presented in this paper was to apply a method for handling two-phase reacting flow for prediction of pulverized coal combustion in large-scale boiler furnace and to assess the ability of the model to predict existing power plant data. The paper presents the principal steps and results of the numerical modeling of power boiler furnace with tangential disposition of the burners. The computational fluid dynamics/computational thermal analysis (CFD/CTA) approach is utilized for creation of a three-dimensional model of the boiler furnace, including the platen superheater in the upper part of the furnace. Standard k-e model is employed for description of the turbulent flow. Coal combustion is modeled by the mixture fraction/probability density function approach for the reaction chemistry, with equilibrium assumption applied for description of the system chemistry. Radiation heat transfer is computed by means of the simplified P-N model, based on the expansion of the radiation intensity into an orthogonal series of spherical harmonics. Some distinctive results regarding the examined boiler performance in capacity range between 65 and 95% are presented graphically. Comparing the simulation predictions and available site measurements concerning temperature, heat flux and combustion efficiency, a conclusion can be drawn that the model produces realistic insight into the furnace processes. Qualitative agreement indicates reasonability of the calculations and validates the employed sub-models. After the validation and verification of the model it was used to check the combustion efficiency as a function of coal dust sieve characteristics, as well as the impact of burners modification with introduction of over fire air ports to the appearance of incomplete combustion, including CO concentration, as well as to the NOx concentration. The described case and other experiences with CFD/CTA stress the advantages of numerical modeling and simulation over a purely field data study, such as the ability to quickly analyze a variety of design options without modifying the object and the availability of significantly more data to interpret the results. .
The essential part of the refractory materials production on a basis of sintered dolomite as raw material is the process of dolomite calcination. The technology process usually takes place in shaft or rotary kilns, where the dolomite stone, CaMg(CO 3 ) 2 , is subjected to a high temperature heat treatment. The calcination of the dolomite is highly endothermic reaction, requiring significant amount of thermal energy to produce sintered dolomite (CaO, MgO), generating a large flow of hot gases at the furnace outlet. The objective of this work was to assess the possibilities of utilization of waste heat of exhaust gases from a shaft kiln in order to improve the overall energy efficiency of the technology process. Several different options were analyzed: (a) preheating of a raw material, (b) preheating of heavy fuel oil, (c) preheating of combustion air, (d) preheating of combustion air and raw material with flue gas, and (e) preheating of air for combustion and for drying of a raw material. Option (e) was selected as the most attractive and therefore it was analyzed in more details, showing significant annual energy savings and relatively short simple payback period on the investment.
An extensive testing programme is performed on a solar collector experimental set-up, installed on a location in Shtip (Republic of Macedonia), latitude 41? 45? and longitude 22? 12?, in order to investigate the effect of the sun tracking system implementation on the collector efficiency. The set-up consists of two flat plate solar collectors, one with a fixed surface tilted at 30? towards the South, and the other one equipped with dual-axis rotation system. The study includes development of a 3-D mathematical model of the collectors system and a numerical simulation programme, based on the computational fluid dynamics (CFD) approach. The main aim of the mathematical modelling is to provide information on conduction, convection and radiation heat transfer, so as to simulate the heat transfer performances and the energy capture capabilities of the fixed and moving collectors in various operating modes. The feasibility of the proposed method was confirmed by experimental verification, showing significant increase of the daily energy capture by the moving collector, compared to the immobile collector unit. The comparative analysis demonstrates a good agreement between the experimental and numerically predicted results at different running conditions, which is a proof that the presented CFD modelling approach can be used for further investigations of different solar collectors configurations and flow schemes.
The paper presents the overall frame, principal steps, and some results of a numerical model of a power boiler furnace that uses pulverized coal, with tangential disposition of the burners. This model demonstrates the application potential of the computational fluid dynamics (CFD) technique and of the computational thermal analysis. Complex three-dimensional furnace geometry, two-phase turbulent flow, coal combustion, and heat transfer have been examined. Two numerical modelling approaches were employed in the investigation, both based on the Euler-Lagrangean two-phase flow concept and on the gas-phase semiempirical k-ɛ turbulence model. The first approach is based on a specially developed comprehensive model of processes in a pulverized coal furnace. In the second case, a commercial CFD code is used to create a three-dimensional furnace model. Some distinctive results concerning the performance of the boiler that was examined are presented graphically. On the basis of a comparison between the simulation predictions and available site measurements, a conclusion can be drawn that these two numerical codes provide realistic insight into furnace processes. Qualitative agreement indicates that the calculations are reasonable and validates the submodels employed.
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