[1] The variability and long-term changes in the ultraviolet (UV) climate in the Netherlands have been studied in relation to ozone and clouds, by analyzing modeled and measured values for daily, monthly, and yearly integrated erythemally weighted UV doses. At Bilthoven, Netherlands (longitude 5.19°E, latitude 52.12°N), UV irradiance measurements for the 1994-2003 period yielded a mean annual dose of 447 ± 29 kJ/m 2 and a mean daily dose of 2.5 ± 0.5 kJ/m 2 for June and July. On average, the maximum UV index exceeded 6.5 (i.e., 0.1625 W/m 2 erythemally weighted) on 10 days per year (21 days in 2003). The mean value of measured-to-modeled ratios of erythemal UV irradiances was 1.00 with a standard deviation of 0.06 for days when the measured global solar radiation agrees within 5% with the cloudless sky value. Three previously introduced approaches to model cloud effects on UV doses were shown to have limitations when applied for low Sun and/or optically thick clouds, while a new approach provided the most consistent results with an average ratio of the measured-to-modeled daily doses of 1.02 and a standard deviation of 0.09, for all seasons and weather conditions for the period 1994-2002. Further analysis also revealed a wavelength dependency of the correlation between global solar radiation and UV radiation. Clouds, on average, reduced the daily dose of erythemal UV to 68% of the clear-sky value, whereas for global solar radiation this was 57%. The modeled annual erythemal UV dose was 622 kJ/m
A transportable reference spectroradiometer for measuring spectral solar ultraviolet irradiance has been developed and validated. The expanded uncertainty of solar irradiance measurements with this reference spectroradiometer, based on the described methodology, is 8.8% to 4.6%, depending on the wavelength and the solar zenith angle. The accuracy of the spectroradiometer was validated by repeated site visits to two European UV monitoring sites as well as by regular comparisons with the reference spectroradiometer of the European Reference Centre for UV radiation measurements in Ispra, Italy. The spectral solar irradiance measurements of the Quality Assurance of Spectral Ultraviolet Measurements in Europe through the Development of a Transportable Unit (QASUME) spectroradiometer and these three spectroradiometers have agreed to better than 6% during the ten intercomparison campaigns held from 2002 to 2004. If the differences in irradiance scales of as much as 2% are taken into account, the agreement is of the order of 4% over the wavelength range of 300-400 nm.
[1] Satellite-derived ultraviolet (UV) irradiances may form the basis for establishing a global UV climatology, provided that their accuracy is confirmed against ground-based measurements of known quality. In this study, quality-checked spectral UV irradiance measurements from four European stations (Sodankyla, Finland; Bilthoven, Netherlands; Ispra, Italy; and Thessaloniki, Greece) are compared with those derived from TOMS, based on the (version 8) data set. The aim of this study is to validate the TOMS UV irradiances and to investigate the origin of disagreements with ground-based data. Comparisons showed that TOMS overestimates summertime noon CIE-weighted irradiances from 6.6% at the high-latitude site of Sodankyla up to 19% for the three other sites. The influence of clouds and aerosols on the observed differences was investigated. For the other three sites (Bilthoven, Ispra, and Thessaloniki), TOMS overestimates the irradiance at 324 nm by almost 15% even under conditions with cloud optical depth of less than 5. For cloud-free days at Ispra and Thessaloniki, differences ranging between 3% and 20% are well correlated with aerosol optical depth.
QASUME is a European Commission funded project that aims to develop and test a transportable unit for providing quality assurance to UV spectroradiometric measurements conducted in Europe. The comparisons will be performed at the home sites of the instruments, thus avoiding the risk of transporting instruments to participate in intercomparison campaigns. Spectral measurements obtained at each of the stations will be compared, following detailed and objective comparison protocols, against collocated measurements performed by a thoroughly tested and validated travelling unit. The transportable unit comprises a spectroradiometer, its calibrator with a set of calibration lamps traceable to the sources of different Standards Laboratories, and devices for determining the slit function and the angular response of the local spectroradiometers. The unit will be transported by road to about 25 UV stations over a period of about two years. The spectroradiometer of the transportable unit is compared in an intercomparison campaign with six instruments to establish a relation, which would then be used as a reference for its calibration over the period of its regular operation at the European stations. Different weather patterns (from clear skies to heavy rain) were present during the campaign, allowing the performance of the spectroradiometers to be evaluated under unfavourable conditions (as may be experienced at home sites) as well as the more desirable dry conditions. Measurements in the laboratory revealed that the calibration standards of the spectroradiometers differ by up to 10%. The evaluation is completed through comparisons with the same six instruments at their homes sites.
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