Sketch artists and the Identi-kit provide face construction techniques widely employed in law enforcement. The effectiveness of these techniques was explored in a study in which 142 subjects worked with artists or Identi-kit technicians to construct from description a sketch or an Identi-kit composite for each of 71 different white-male target faces. The artists and technicians also prepared a sketch and composite while directly viewing each target face. Ratings of goodness of fit between the sketches/composites and photographs indicated that sketches were superior to composites. Artist differences were found, but technician differences were minimal. Sketches from view were better than from description, but the description-view variable did not affect composites. These latter two results indicate that the Identi-kit technique may have serious limits in representation accuracy. Time-line analyses of work on various features revealed that subjects "move around" more and take longer in constructing sketches. Results are discussed in terms of the utility of these and other face construction procedures.
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In the theory of the specific heats of gases of diatomic molecules the functionplays a well-known and important part. The rotational specific heat Crot of a diatomic molecule, which is susceptible of representation as a rigid body with two equal principal moments of inertia, without spin about the other principal axis, is given bywhere R is the gram-molecular gas-constant andthe pair of equal moments of inertia being equal to A. Whether such a model is or is not an adequate representation is a matter for determination by a detailed study of the structure of the band spectrum, particularly of the nature of the normal electronic and vibrational state. It is known to be applicable to normal molecules of the halogen hydrides, to CO and other molecules which have a normal state of type 1S including (but for a certain special feature) H2.
The commonest form of Langmuir's adsorption isotherm iswhere θ is the fraction of the surface of the solid covered by adsorbed molecules, p the gas pressure in equilibrium with the adsorbed layer and A = A (T) a function of the temperature alone. This formula is usually derived by a kinetic argument which balances the rates of deposition and re-evaporation. It is perhaps not without interest to show that formula (1) and similar formulae can be obtained directly by the usual statistical methods which evaluate all the properties of the equilibrium state of any assembly. The ordinary derivation is apt to obscure the essentially thermodynamic character of (1) and to lead one to think that its form depends on the precise mechanisms of deposition and re-evaporation, whereas in fact it depends only on the whole set of states, adsorbed and free, accessible to the molecules in question. By suitable use of the usual technique for handling assemblies obeying the Fermi-Dirac statistics the saturation effect can be naturally incorporated in the theory ab initio.
1. In a recent note I showed that Langmuir's adsorption isothermwhere θ is the fraction of the surface covered by adsorbed gas, p the gas pressure in equilibrium with it, and A (T) a specified function of the temperature, can be derived as a theorem in statistical mechanics without any appeal to the mechanism of deposition and re-evaporation. Necessary and sufficient assumptions for the truth of (1) are that the atoms (or molecules) of the gas are adsorbed as wholes on to definite points of attachment on the surface of the adsorber, that each point of attachment can accommodate one and only one adsorbed atom, and that the energies of the states of any adsorbed atom are independent of the presence or absence of other adsorbed atoms on neighbouring points of attachment. Under these assumptions the explicit form of (1) iswhere m is the mass of the adsorbed atom or molecule, bg(T) the partition function for its internal states in the gas phase, and vs(T) the partition function for its set of adsorbed states. These sets of states are to be so specified that the energy zero is assigned tot the lowest state of each set in constructing bg(T) and vs(T), and then X is the energy required to transfer a molecule from the lowest adsorbed state tot the lowest gas state. Quite another adsorption isotherm was shown to hold when adsorption of a molecule takes place as atoms and requires two or more points of attachment.
Investigations are also being carried out upon potassium and rubidium, in order to test out the conjecture, that the weak radioactivity of these elements is due to the presence of minute traces of the unknown alkali element with atomic number 87.
We consider an ideal problem of adsorption of single and double particles upon a solid surface which has its sites of accommodation regularly arranged, and by comparing the equilibrium properties obtained by Bethe's method with the ordinary statistical formulae, we obtain approximate expressions for:(1) g(N, n, X), the number of ways of arranging n particles upon N sites of a lattice so that the number of neighbouring sites occupied by the particles is X.(2) g2(N, n, X), the number of ways of arranging n double particles upon N sites so that each of the double particles takes up two adjacent sites and the number of neighbouring sites occupied by two different particles is X.Both these expressions are found to agree with the exact values when the N sites lie on a straight line. When we use the first expression to construct the configurational partition functions of certain physical assemblies and expand them in powers of 1/kT, they are found to agree with the corresponding rigorous expressions as far as (1/kT)3, which is the highest power which we can find rigorously at present. With the help of the first expression, formal equations for superlattice formation in an alloy with the composition 1: 1 and equations for the separation into phases of regular liquids are given. Lastly we show that atoms and molecules in a regular liquid may dissociate or recombine suddenly accompanied by a latent heat. This is a new cooperative phenomenon, which may bear some resemblance to the melting process between the solid and liquid states.
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