Abstract:The Alxa block is located in the southwestern margin of the North China Craton. The Paleoproterozoic tectonic evolution, crustal growth and tectonic affinity of the block remain unknown or controversial. The Longshoushan (LS) area is one of the few areas that outcrop Paleoproterozoic to crystalline basement rocks in the Alxa Block. In this study, we preset whole-rock geochemistry, zircon U-Pb geochronology and Lu-Hf isotope data from metagabbro, metadiorite, quartz syenite, granitic leucosome and pegmatoid leucosome in the LS area. These rocks all are enriched in LREE and LILE, and depleted in HREE and HFSE. Eight new LA-ICP-MS zircon U-Pb ages yielded three magmatic ages of 2044 Ma, 2029 Ma and 1940 Ma, and three metamorphic ages of 1891 Ma, 1848 Ma and 1812 Ma. Lu-Hf analyses reveal that the magmatic zircons and anatectic/metamorphic zircons from all the rock types are characterized by positive εHf(t) (−0.16 to 10.89) and variable εHf(t) (−11.21 to 6.24), respectively. Based on the previous studies and our new data, we conclude that the LS area experienced three magmatic events (2.5-2.45 Ga, 2.1-2.0 Ga and~1.95-1.91 Ga) and three regional metamorphism/anataxis events (~1.93-1.89 Ga, 1.86-1.84 Ga and~1.81 Ga) in Paleoproterozoic. The age-Hf isotope data establishes two main crustal growth events at~2.9-2.5 Ga and~2.2-2.0 Ga in the LS area. These data indicate that the LS area experienced intraplate extensional setting in the middle Paleoproterozoic, and continental subduction, collision and exhumation in the late Paleoproterozoic. Combining the geochronological framework and tectonic evolution, we suggest that the Alxa Block is part of the Khondalite Belt.
The giant Jinchuan nickel-copper-platinum-group element (PGE) deposit is hosted by two individual sub-vertical intrusions, referred to as the western and eastern intrusions (including segment II-W and segment II-E). Exactly how the Jinchuan deposit was formed by a system of sub-vertical magma conduits is still not well understood. This paper reports new major elements, trace elements and PGEs data from the Jinchuan deposit to study the formation mechanism of sulfide ores with different textures and their relationship with the magma conduit system. Our study shows that the PGE tenors of disseminated and net-textured sulfide in segment II-E are significantly lower than segment II-W and the western intrusion, but the Cu/Pd ratios are opposite. In addition, net-textured sulfides in segment II-W show a negative correlation between IPGE (Ir, Ru and Rh) and PPGE (Pt and Pd) in contrast to the positive correlation in segment II-E and the western intrusion. These features indicate the parental magma sources of the western intrusion, segment II-W and segment II-E were originally three different surges of PGE-depleted magma. Modeling of parental magma in the western intrusion, segment II-W and segment II-E suggests that they were formed by the same initial picritic basalt (100 ppm Cu, 1 ppb Ir and 10 ppb Pd) with different prior sulfide segregations (0.0075%, 0.0085% and 0.011%). The three parts of Jinchuan sulfides show that the Pt/Pd and (Pt + Pd)/(Ir + Ru + Rh) ratios decrease from section III-5 toward both sides in the western intrusion and decrease from section II-14 toward all sides, whereas no regular spatial variations occur in segment II-E, showing the different fractionation processes of sulfide melt. The massive sulfides in the western intrusion and segment II-E experienced a ~20% to 40% and ~40% to 60% fractionation of sulfide melt, respectively. We propose that the Jinchuan deposit was generated in a metallogenic system of multiple magma conduits, where sulfides entrained in parental magma experienced different amounts of prior removal.
The North Qilian orogenic belt in North China has been defined as a subduction–collision zone between the Alxa Block and the Qilian Block. We present petrography, zircon U–Pb geochronology, major- and trace-element geochemistry, and Sr–Nd–Pb–Hf isotope analysis for the Yushigou diabase from the Longshoushan area, which is located SW of the Alxa Block, aiming to understand its petrogenetic link to subduction processes. The Yushigou diabase belongs to the tholeiite series, and shows enrichment in light rare earth and large-ion lithophile elements, and a depletion in heavy rare earth and high-field-strength elements. Laser ablation – inductively coupled plasma – mass spectrometry U–Pb zircon dating yielded an emplacement age of 414 ± 9 Ma, with an ϵHf(t) value in the range of −10.3 to 1.8. The whole-rock initial 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of the diabase range over 16.811–17.157, 15.331–15.422 and 37.768–37.895, respectively. The (87Sr/86Sr)i ratios vary between 0.7086 and 0.7106, and ϵNd(t) values vary between −14.4 and −13.4, which are significantly higher than the ϵHf(t) value (Nd–Hf decoupling). An interpretation of the elemental and isotopic data suggests that the Yushigou diabase was derived from partial melting of an enriched mantle I (EM-I) -type lithospheric mantle in the spinel–garnet transitional zone. Based on the geochemical features and previous regional geological data, we propose that the Silurian magmatism was most likely triggered by slab break-off after the closure of the North Qilian Ocean, and ancient continental materials from the subduction slab metasomatized the overlying lithospheric mantle during exhumation.
Abstract. Middle–Late Jurassic high-Sr/Y granitic intrusions are
extensively exposed in the Liaodong Peninsula in the eastern part of the
North China Craton (NCC). However, the genesis of the high Sr/Y signature in
these intrusions has not been studied in detail. In this study, we report
results of zircon U–Pb dating, Hf isotopic analysis, and zircon and
whole-rock geochemical data for the Late Jurassic Zhoujiapuzi granite in the
middle part of the Liaodong Peninsula. The Zhoujiapuzi granite is high-K
(calc–alkaline) and peraluminous in nature, with high SiO2 (68.1 wt %–73.0 wt %) and Al2O3 (14.5 wt %–16.8 wt %), low TFe2O3
(1.10 wt %–2.49 wt %) and MgO (0.10 wt %–0.44 wt %), and high Sr/Y
(19.9–102.0) and LaN/YbN (14.59–80.40), which is characteristic of high-Sr/Y I-type granite. The geochemical signatures, in combination with the
presence of a large number of Paleoproterozoic inherited zircons, indicate
that the Zhoujiapuzi granite was most likely derived from partial melting of
the basement in the region, specifically the Liaoji granites. The high
Sr/Y signature is inherited from these source rocks. Laser ablation–inductively coupled plasma mass spectrometer (LA-ICP-MS) zircon U–Pb
dating of the autocryst zircons from two samples (from different localities)
yielded consistent weighted average ages of 160.7 ± 1.1 Ma (mean squared weighted deviation – MSWD = 1.3)
and 159.6 ± 1.1 Ma (MSWD = 1.2), with εHf(t) values in the
range of −26.6 to −22.8. Morphological and chemical studies on autocrystic
zircon grains show that there are two stages of zircon growth, interpreted
as magmatic evolution in two distinct stages. The light-cathodoluminescence (light-CL) core reflects a
crystallization environment of low oxygen fugacity and high TZr–Ti; the
dark-CL rim formed with high oxygen fugacity and lower TZr–Ti. Based on
the geochemical features and regional geological data, we propose that the
Liaodong Peninsula in the Late Jurassic was part of a mature continental
arc, with extensive melting of thick crust above the Paleo-Pacific
subduction zone.
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