ABSTRACT:The near infrared spectroscopy (NIRS) has shown a rapid and accurate technique for evaluation of materials of biological origin. The objective of this study was to evaluate the ability of the near infrared (NIR) spectroscopy associated to the Principal Component Analysis (PCA) for the separation of carbonization processes and identification of the origin of the woods used in the carbonizations. Hence, the charcoal of seven species of Eucalyptus and twenty native species from the Cerrado (savannah) of Minas Gerais, Brazil were investigated. The Eucalyptus wood was carbonized in a laboratory furnace and in a 190 m 3 industrial rectangular kilns while the wood of native vegetation was carbonized only under laboratory conditions. The samples were grinded for NIR spectra acquirement. The NIR spectra were analyzed by PCA but no cluster were identified allowing discrimination between charcoal produced from native and from Eucalyptus wood. However, the cluster formed in the PCA when using the first derivative NIR spectra permitted to distinguish charcoal produced in different processes of carbonization. Two groups of data for charcoal produced in the industrial rectangular kilns were also observed, suggesting heterogeneity in the carbonization process.Key words: Charcoal origin, NIRS, principal component analysis. USO DA ESPECTROSCOPIA NO INFRAVERMELHO PRÓXIMO PARA DIFERENCIAR PROCESSOS DE CARBONIZAÇÃO E FONTES DE CARVÃO VEGETAL RESUMO: A espectroscopia no infravermelho próximo (NIRS) tem se apresentado uma técnica rápida e precisa para a avaliação de materiais de origem biológica. Objetivou-se, neste trabalho, avaliar a habilidade da espectroscopia no infravermelho próximo, em conjunto com Análise de Componente Principal (PCA), para separação dos processos de carbonização e a identificação de madeiras usadas na carbonização. Para isso foram realizadas carbonizações de sete espécies de Eucalyptus e vinte espécies nativas do
The reaction wood is formed in an attempt to remain upright tree in response to the action of forces such as winds, irregular crown or slope of the land that tend to incline it. In hardwoods, as in Eucalyptus, this type of wood is called tension wood and occurs in the region of the stem facing the face of force application. Indicative of the presence of this type of wood is the high shrinkage and basic density compared to normal wood. Once the basic density and shrinkage are parameters for determining the quality of the wood, this study aimed to evaluate the variation of basic density and shrinkage of opposite and tension wood along the radius in four species of Eucalyptus sp. Four tree species Eucalyptus camaldulensis, Eucalyptus maculata, Eucalyptus pilularis and Eucalyptus urophylla, with 32 years of age, were taken from an experimental planting of the Federal University of Lavras. Specimens were made to represent the diametrical variation of the opposite of tension wood in disks cut at the dbh. The results indicate that the properties of radial, tangential and volumetric shrinkage, coefficient of anisotropy and basic density did not differ statistically between the tensionand opposite wood.
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