The rheological behavior of coffee extract with different water contents (49 to 90%) was studied at a wide range of temperatures (274 to 365 K) using a concentric cylinder rheometer. The flow curves followed different models depending on the concentration and temperature level. Newtonian behavior was observed at high values of water content and temperature, changing to power law as these values were decreased. The Newtonian viscosity as well as the consistency and behavior index could be well correlated by functions simultaneously dependent on temperature and water content. The rheological parameters, together with experimental values of pressure loss in tube flow, were used to calculate friction factors. These showed to be in good agreement with those resulting from classical theoretical and empirical equations, thus confirming the reliability of the rheological measurements.

The comprehension of the structure of starch granules is important for the understanding of its physicochemical properties. Native and sour cassava starches after being analyzed with respect to their pasting properties and baking expansion capacity, were treated with 2.2 N HCl at 38 °C for a maximum of nine days. The starch granules remaining after lintnerization were analyzed for amylose content and intrinsic viscosity, by X-ray diffraction, scanning electron microscopy and chromatographic analysis. The results indicated that the acid hydrolysis on all starches occurred in two steps. The first one, with high hydrolysis rate, was characterized by a quick degradation of the amorphous part of the granules whereas the second step, with lower hydrolysis rate, was characterized by a higher resistance of the organized areas of the granules to acid treatment. Most of the amylose chains were found in the amorphous areas of starch granules only a small percentage was involved in the crystalline regions. The microscopic and chromatographic analysis demonstrated that the acid hydrolysis was not able to disrupt the entire granular crystalline structure. Fermented starch showed amylose and/or amylopectin chain fractions resistant to pullulanase, probably due to structural alterations during fermentation.

Rheological and thermophysical properties were determined for blackberry juice, which was produced from blackberry fruit at 9.1 0.5°Brix and density of 1.0334 0.0043 g cm -3 . The concentration process was performed using a roto evaporator, under vacuum, to obtain concentrated juice at about 60 °Brix. In order to obtain different concentrations, concentrated juice was diluted with distilled water. Rheological measurements were carried out using a Rheotest 2.1 Searle type rheometer. In the tested ranges, the samples behaved as pseudoplastic fluids, and the PowerLaw model was satisfactorily fitted to the experimental data. The friction factor was measured for blackberry juice in laminar flow conditions of pseudoplastic behavior. Thermal conductivity, thermal diffusivity and density of blackberry juice at 9.4 to 58.4 °Brix were determined, in triplicate, at 0.5 to 80.8 °C. Polynomial regression was performed to fit experimental data obtaining a good fit. Both temperature and concentration showed a strong influence on thermophysical properties of blackberry juice. Calculated apparent specific heat values varied from 2.416 to 4.300 kJ.kg -1 °C in the studied interval. Keywords: fruit juice; rheology; thermal conductivity; thermal properties. ResumoAs propriedades reológicas e termofísicas foram determinadas para suco de amora produzido a partir da fruta com 9.1 0.5 °Brix e densidade de 1,0334 0,0043 g cm -3 . O processo de concentração foi realizado utilizando-se um roto evaporador, sob vácuo, obtendo-se o suco concentrado em aproximadamente 60 °Brix. As diferentes concentrações foram obtidas a partir da diluição do suco concentrado em água destilada. As medidas reológicas foram conduzidas utilizando-se o reômetro Rheotest 2.1 do tipo Searle. Em todos os experimentos as amostras apresentaram um comportamento pseudoplástico, e o modelo da Lei da Potência foi ajustado satisfatoriamente aos dados experimentais. O fator de atrito foi medido para o suco em regime laminar com comportamento pseudoplástico. A condutividade térmica, a difusividade térmica e a densidade foram determinadas em triplicata para o suco de amora nas faixas de 9,4 a 58,4 °Brix e de 0,5 a 80,8 °C.A temperatura e a concentração mostraram forte influência nas propriedades termofísicas do suco de amora. Os valores do calor específico aparente variaram de 2,416 a 4,300 kJ.kg -1 °C. Palavras-chave: condutividade térmica; propriedades térmicas; reologia; suco de fruta.

The rise in boiling point of coffee extract was experimentally measured at soluble solids concentrations in the range of 9.2 to 52.4ºBrix and pressures between 5.8 × 10³ and 9.4 × 10(4) Pa (abs.). Different approaches to representing experimental data, including the Dühring's rule, the Antoine equation and empirical models proposed in the literature were tested. In the range of 9.2 to 16.2ºBrix, the rise in boiling point was nearly independent of pressure, varying only with extract concentration. Considerable deviations of this behavior began to occur at concentrations higher than 16.2ºBrix. Experimental data could best be predicted by adjusting an empirical model which consists of a single equation that takes into account the dependence of rise in boiling point on pressure and concentration

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Molasses is a by-product from the raw sugarcane industry with vast applications in the production of ethanol biofuel. A good knowledge of the rheological properties of this raw material is of crucial importance when designing and optimizing unit operations involved in processing it. The present work thus aims to study the rheological behavior of molasses at solid concentrations ranging from 20 to 70 o Brix and temperatures between 21 and 988C using a concentriccylinder rheometer. Experimental results showed Newtonian behavior in concentrations of 20 and 40 o Brix and pseudoplastic behavior in concentrations of 50 and 70 o Brix. For these results, the Power Law models presented the best fitting results. In addition, the dependence of the flow behavior index and the flow consistency index of the Power Law model on temperature and solid concentration was also successfully modeled through a polynomial model and an Arrhenius-type equation, respectively.

The rheological behavior and density of goat milk was studied as a function of solids concentration (10.5 to 50.0%) and temperature (273 to 331 k). Newtonian behavior was observed for values of total solids (TS) between 10.5 and 22.0% and temperatures from 276 to 331 k changing to pseudoplastic behavior without yield stress for TS from 25.0 to 39.4% at the same range of temperature. Goat milk with TS between 44.3 to 50.0% and temperatures of 273 to 296 k showed yield stress in addition to pseudoplastic behavior. At 303 to 331 k the power law model was observed again, without yield stress. The density of goat milk ranged from 991.7 to 1232.4 kg.m-3.