We have successfully synthesized vertically aligned ZnO nanotube arrays by metalorganic chemical vapor deposition. Since no metal catalysts are used in this work, the growth process of ZnO nanotube arrays does not follow a vapor-liquid-solid mechanism but a self-catalyzed growth mechanism. X-ray diffraction results show that the nanotubes have ZnO hexagonal wurizite structures and only the ZnO (0002) peak can be seen. The rocking curve also shows a full width at half-maximum value of similar to 1625 arc second. A 6-fold symmetry in phi-scan data is also observed, indicating in-plane alignment of ZnO nanotube arrays. Room temperature photoluminescence results present a high optical quality and nearly defect-free crystal structure of ZnO nanotube at-rays. Moreover, the high near-band edge emission to deep level emission intensity ratio (I(NBE)/I(DLE)) of 2050 is obtained
This study evaluates the effect of crystallinity and point defects on time-dependent photoresponsivity and the cathodoluminescence (CL) properties of β-Ga₂O₃ epilayers. A synchrotron high-resolution X-ray technique was used to understand the crystalline structure of samples. Rutherford backscattering spectroscopy was used to determine the net chemical composition of the samples to examine the type and ratio of their possible point defects. The results show that in functional time-dependent photoresponsivity of photodetectors based on β-Ga₂O₃ epilayers, point defects contribution overcomes the contribution of crystallinity. However, the crystalline structure affects the intensities and emission regions of CL spectra more than point defects.
In this study, indium-tin oxide (ITO)/Al-doped zinc oxide (AZO) composite films were fabricated by pulsed laser deposition and used as transparent contact layers (TCLs) in GaN-based blue light emitting diodes (LEDs). The ITO/AZO TCLs were composed of the thin ITO (50 nm) films and AZO films with various thicknesses from 200 to 1000 nm. Conventional LED with ITO (200 nm) TCL prepared by E-beam evaporation was fabricated and characterized for comparison. From the transmittance spectra, the ITO/AZO films exhibited high transparency above 90% at wavelength of 465 nm. The sheet resistance of ITO/AZO TCL decreased as the AZO thickness increased, which could be attributed to the increase in a carrier concentration, leading to a decrease in the forward bias of LED. The LEDs with ITO/AZO composite TCLs showed better light extraction as compared to LED with ITO TCL in compliance with simulation. When an injection current of 20 mA was applied, the output power for LEDs fabricated with ITO/AZO TCLs had 45%, 63%, and 71% enhancement as compared with those fabricated using ITO (200 nm) TCL for the AZO thicknesses of 200, 460, and 1000 nm, respectively.
This study demonstrates the flexible white LED structure with high lumen efficiency and uniform optical performance for neutral white and warm white CCT. Flip-chip LEDs were attached on a polyimide substrate with copper strips as electrical and thermal conduction paths. Yellow phosphors are mixed with polydimenthysiloxane (PDMS) to provide mechanical support and flexibility. The light efficiency of this device can reach 120 lm/W and 85% of light output uniformity of the emission area can be achieved. Moreover, the optical simulation is employed to evaluate various designs of this flexible film in order to obtain uniform output. Both the pitch between the individual devices and the thickness of the phosphor film are calculated for optimization purpose. This flexible white LED with high lumen efficiency and good reliability is suitable for the large area fixture in the general lighting applications.
Growth of InGaN, having high Indium composition without compromising crystal quality has always been a great challenge to obtain efficient optical devices. In this work, we extensively study the impact of non-radiative defects on optical response of the plasma assisted molecular beam epitaxy (PA-MBE) grown InGaN nanowires, emitting in the higher wavelength regime (
λ
>
520
nm). Our analysis focuses into the effect of defect saturation on the optical output, manifested by photoluminescence (PL) spectroscopy. Defect saturation has not so far been thoroughly investigated in InGaN based systems at such a high wavelength, where defects play a key role in restraining efficient optical performance. We argue that with saturation of defect states by photo-generated carriers, the advantages of carrier localization can be employed to enhance the optical output. Carrier localization arises because of Indium phase segregation, which is confirmed from wide PL spectrum and analysis from transmission electron microscopy (TEM). A theoretical model has been proposed and solved using coupled differential rate equations in steady state to undertake different phenomena, occurred during PL measurements. Analysis of the model helps us understand the impact of non-radiative defects on PL response and identifying the origin of enhanced radiative recombination.
This study proposes a novel packaging structure for vertical thin-GaN LED applications by integration of LED chip and silicon-based packaging process. The vertical thin film LED is directly mounted on package submount. The shortest thermal path structure from junction to package submount achieves the lowest thermal resistance of 1.65 K/W for LED package. Experimental results indicate that low thermal resistance significant improved forward current up to 4.6A with 1.125 × 1.125 mm² LED chip size.
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