The solid-state structure of the title compound, C32H40N2O2, is characterized by benzoxazine units with a cisoid geometry, and with the N atoms displaced from the planes of the heterocycles. The two benzoxazine groups are nearly coplanar.
A neutral aminotrithioether interacts with CuI, generating a coordination polymer in the solid state. Electrochemical studies indicate that the ligand is prone to oxidation by CuII, which results in a novel C-C bond formation reaction.
The title compound, C20H27NOS, was obtained from the corresponding O-thiocarbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp
3-hybridized S atom [C—S—C = 101.66 (1)°]. The steric bulk of the 1-adamantyl substituent on the 2-position of the aromatic ring is reflected in the S—C—C—C torsion angle [−7.5 (3)°].
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