No abstract

The Songhua River is one of the most populated and oldest industrial areas in Northeast China. To understand the sources and distribution of polycyclic aromatic hydrocarbons and their derivatives, such as 16 priority (PAHs), 33 methylated (Me-PAHs), and 12 nitrated (NPAHs) in river water and sediment, were noticed. The concentrations of ∑PAHs, ∑Me-PAHs, and ∑NPAHs in river water scaled from 135 to 563, 9.36 to 711, and 1.26 to 64.7 ng L−1, with mean values of 286, 310, and 17.9 ng L−1, and those in sediments were from 35.8 to 2000 ng g−1, 0.62 to 394 ng g−1, and 0.28 to 176 ng g−1 (dry weight) with mean values of 283, 103, and 21.7 ng g−1. The compositions proved that two-ring and three-ring compounds of PAHs, NPAHs, and four-ring, six-ring of Me-PAHs were prevalent in water samples; in contrast, four-ring dominated in sediments. Principal components analysis (PCA) and diagnostic ratios confirmed that pollutant source was mixed petrogenic and pyrogenic origin. The fugacity fraction (ƒƒ) was also calculated to explain the trend of sediment–water exchange, high ƒƒ values found in summer, for most HMW PAHs and Me-PAHs that these substances acted as a secondary source of emissions from sediment to water. The risk assessment for water was categorized as high.

polycyclic aromatic hydrocarbons (PAHs), 33 Methylated PAHs (Me-PAHs), and 14 nitrated PAHs (NPAHs) were measured in wastewater treatment plants (WWTPs) to study the removal efficiency of these compounds through the WWTPs, as well as their source appointment and potential risk in the effluent. The concentrations of ∑PAHs, ∑Me-PAHs, and ∑NPAHs were 2.01–8.91, 23.0–102, and 6.21–171 µg/L in the influent, and 0.17–1.37, 0.06–0.41 and 0.01–2.41 µg/L in the effluent, respectively. Simple Treat 4.0 and meta-regression methods were applied to calculate the removal efficiencies (REs) for the 63 PAHs and their derivatives in 10 WWTPs and the results were compared with the monitoring data. Overall, the ranges of REs were 55.3–95.4% predicated by the Simple Treat and 47.5–97.7% by the meta-regression. The results by diagnostic ratios and principal component analysis PCA showed that “mixed source” biomass, coal composition, and petroleum could be recognized to either petrogenic or pyrogenic sources. The risk assessment of the effluent was also evaluated, indicating that seven carcinogenic PAHs, Benzo[a]pyrene, Dibenz[a,h]anthracene, and Benzo(a)anthracene were major contributors to the toxic carcinogenic equivalents (TEQs) in the effluent of WWTPs, to which attention should be paid.

This paper assesses the occurrence, distribution, source, and toxicity of polycyclic aromatic hydrocarbons (PAHs), and their methylated form (Me-PAHs) in sewage sludge from 10 WWTPs in Northeastern China was noted. The concentrations of ∑PAHs, ∑Me-PAHs ranged from 567 to 5040 and 48.1 to 479dw, which is greater than the safety limit for sludge in agriculture in China. High and low molecular weight 4 and 2-ring PAHs and Me-PAHs in sludge were prevalent. The flux of sludge PAHs and Me-PAHs released from ten WWTPs, in Heilongjiang province, was calculated to be over 100 kg/year. Principal component analysis (PCA), diagnostic ratios and positive matrix factorization (PMF) determined a similar mixed pyrogenic and petrogenic source of sewage sludge. The average values of Benzo[a]pyrene was below the safe value of 600 dependent on an incremental lifetime cancer risk ILCR of 10−6. Sludge is an important source for the transfer of pollutants into the environment, such as PAHs and Me-PAHs. Consequently, greater consideration should be given to its widespread occurrence.