A Cd(ii)-based coordination compound, [CdI2(4-nvp)2] (1), has been synthesized using CdI2 and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp).

( E )- N ′-((2-Hydroxynaphthalen-1-yl)methylene)picolinohydrazide (H-PNAP) shows aggregation-induced emission (AIE) strictly in a 90% water/MeOH (v/v) mixture at 540 nm, and the solid-state emission is blue-shifted to 509 nm upon excitation at 400 nm. The AIE activity of H-PNAP is selectively quenched by 2,4,6-trinitrophenol (TNP) and 2,4-dinitrophenol (DNP) out of different nitroaromatic compounds with a limit of detection (LOD) of 7.79 × 10 –7 and 9.08 × 10 –7 M, respectively. The probe is nonemissive in aqueous medium (4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid, HEPES buffer, pH 7.2); however, it shows a strong emission to Al 3+ (λ em , 490 nm) in the presence of 17 other biological metal ions, and the LOD is 2.09 nM which is far below the WHO recommended value (7.41 mM). The emission of the [Al(PNAP)(NO 3 ) 2 ] complex is quenched by HF 2 – (F – and PO 4 3– are weak quencher), and the LOD is as low as 15 nM. The probable mechanism of the sensing feature of the probe has been authenticated by 1 H nuclear magnetic resonance titration, mass spectrometry, Fourier transform infrared spectroscopy, Benesi–Hildebrand plot, and Job’s plot in each case. The probe has some practical applications such as recovery of Al 3+ from the drinking water sample, construction of the INHIBIT logic gate, and detection kits for Al 3+ and TNP/DNP by simple paper test strips. The probe, H-PNAP, has successfully been applied to the detection of intracellular Al 3+ and HF 2 – ions in the human breast cancer cell, MDA-MB-468.

A single fluorescence probe recognizes multiple ions and grabs the great attention of scientists.

Designing a small organic molecule for fluorescence sensing and electrical conductivity is a challenging task.

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Binuclear Cu(ii)-acetylenedicarboxylate assembled through extensive hydrogen bonding and C–H⋯π interactions to make 3D supramolecular aggregate behaves as light sensing electronic device.

Coumarinyl-rhodamine, HCR, served as an extremely selective sensor for Pd2+ ions in ethanol/H2O (8 : 2, v/v, HEPES buffer, pH 7.2) solution and the limit of detection (LOD) was 18.8 nM (3σ method).