Holey 2D metal oxides have shown great promise as functional materials for energy storage and catalysts. Despite impressive performance, their processing is challenged by the requirement of templates plus capping agents or high temperatures; these materials also exhibit excessive thicknesses and low yields. The present work reports a metal‐based coordination polymer (MCP) strategy to synthesize polycrystalline, holey, metal oxide (MO) nanosheets with thicknesses as low as two‐unit cells. The process involves rapid exfoliation of bulk‐layered, MCPs (Ce‐, Ti‐, Zr‐based) into atomically thin MCPs at room temperature, followed by transformation into holey 2D MOs upon the removal of organic linkers in aqueous solution. Further, this work represents an extra step for decorating the holey nanosheets using precursors of transition metals to engineer their band alignments, establishing a route to optimize their photocatalysis. The work introduces a simple, high‐yield, room‐temperature, and template‐free approach to synthesize ultrathin holey nanosheets with high‐level functionalities.
The present work reports a simple and rapid disassembly/reassembly approach at room temperature to tailor functional metal oxides of 2D and 3D architectures.
Well-defined second-generation hot spots in end-to-end assembled gold nanobipyramids exhibit sufficient enhancement of the plasmonic field for single molecule detection.
Inspired by the design and performance of biological pores, polymer functionalization of nanopores has emerged as an evolving field to advance transport performance within the last few years.
The versatile qualities of gold coated magnetic nanoparticles for both optical and electrochemical detection, as well as the separation of analytes, make them an excellent choice for ultrasensitive biosensing applications.
A corrosion cup test was undertaken using BaAl 2 Si 2 O 8 and Al4.1Zn3.2Mg alloy, heated in air for 150 h at 850°C. Electron probe microanalysis, X-ray diffraction, and scanning electron microscopy coupled with energy dispersive spectroscopy were used to identify the mineralogical and microstructural changes at the interfaces. The microstructural results revealed three microstructural areas: (1) Spinel layer with large numbers of Al alloy channels; (2) interfacial area with mainly alumina, spinel, and BaAl 2 Si 2 O 8 ; and (3) interdiffusion zone chemically close to barium hexaaluminate. The principal observations are:1. BaAl 2 Si 2 O 8 was highly resistant to molten Al alloy corrosion owing to sluggish kinetics, as evidenced by the observation of unreacted BaAl 2 Si 2 O 8 grains in the interfacial area. 2. The nature of the microstructure, particularly an interdiffusion zone instead of a continuous layer of precipitated alumina at the interface between the Al alloy channels and the unreacted BaAl 2 Si 2 O 8 supports the conclusion that the corrosion mechanism is governed by interdiffusion (Si/Ba and Al/Mg) and substitution. 3. The formation and limited retention of an MgO layer at the metal-ceramic interface played a critical role in alloy oxidation and the consequent interfacial phenomena.
Surface-enhanced Raman scattering (SERS) probes offer considerable opportunities in label-based biosensing and analysis. However, achieving specific and reproducible performance, where low detection limits are needed in complex media, remains a challenge. Herein, we present a general strategy employing gold nanorod SERS probes and rationally designed surface chemistry involving protein resistant layers and antibodies to allow for the selective detection of species in complex media. By utilizing the ability of gold nanorods for selective surface modification, Raman reporters (4-mercaptobenzoic acid) were attached to the tips. Importantly, the sides of the nanorods were modified using a mixed layer of two different length stabilizing ligands (carboxyl-terminated oligo ethylene glycols) to ensure colloidal stability, while antibodies were attached to the stabilizing ligands. The nanoparticle interfacial design improves the colloidal stability, unlocks the capability of the probes for targeting biomolecules in complex matrices, and gives the probes the high SERS efficiency. The utility of this probe is demonstrated herein via the detection of Salmonella bacteria at the single bacterium level in complex food matrices using an anti-Salmonella IgG antibody-conjugated probe. The modular nature of the surface chemistry enables the SERS probes to be employed with a molecularly diverse range of biorecognition species (e.g., antibodies and peptides) for many different analytes, thus opening up new opportunities for efficient biosensing applications.
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