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Herein, we have successfully demonstrated a nanofiller (such as multiwalled carbon nanotubes (MWCNT)) dispersed in a polymer matrix (such as polyacrylonitrile (PAN)) as an effective pore filling agent to a microporous Daramic membrane for inhibiting bromine diffusion in zinc bromine redox flow batteries. A simple protocol of the MWCNT/ PAN-Daramic membrane renders a major benefit for inhibiting bromine diffusion relative to the conventional microporous membrane. As a result, the MWCNT/PAN composite Daramic membrane exhibits remarkable electrochemical performance in zinc bromine redox flow batteries at various current densities. More impressively, the MWCNT/PAN composite Daramic membrane shows a 90% Coulombic efficiency compared to the pristine Daramic membrane and the PAN composite Daramic membrane with only 68.53 and 71.20% efficiencies at 160 mA cm −2 , respectively. Moreover, the MWCNT/PAN composite Daramic membrane displays an extraordinary long cycling performance with a >97% Coulombic efficiency, whereas the Daramic membrane withstands only 200 cycles due to severe water transport from the catholyte to the anolyte. The zinc bromine redox flow battery assembled with the MWCNT/ PAN composite Daramic membrane significantly reduces the self-discharge rate and retains an open circuit voltage of 1.69 V for 13.40 h in comparison to the Daramic membrane (10.83 h) and the PAN composite membrane (11.13 h). Thus, the extraordinary flow cell performance and stability of the MWCNT/PAN composite Daramic membrane lead to the development of an alternative to the microporous Daramic membrane in zinc bromine redox flow batteries.

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