A determination of the structure of the title compound, C3H7NO2, leads to an accurate description of its molecular dimensions and crystal packing. As in the structure of the L-isomer, the molecules aggregate into alternating layers, each consisting of only one type of isomer. The molecules in each layer are interconnected through head-to-tail sequences generated by a cell translation and a 2(1) screw axis. Adjacent layers are interconnected by head-to-tail sequences generated by a glide plane.
In the title compound, C5H11NO2S, the conformation of the terminal methyl C atom with respect to the β‐C atom is trans. The crystal structure is stabilized by a network of characteristic head‐to‐tail dl1 and dl2 sequences.
Key indicatorsSingle-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.028 wR factor = 0.078 Data-to-parameter ratio = 7.2 For details of how these key indicators were automatically derived from the article, see
In the title compound, C2H6NO2+.C2HO4-, the glycine molecule exists in the cationic form and the oxalic acid molecule in the mono-ionized state. The molecules aggregate into alternate columns of glycinium and semi-oxalate ions. The structure is stabilized by an extensive network of hydrogen bonds.
In the title compound, C5H12NO2S+·C4H3O4−, the methionine molecule exists in the cationic form and the maleic acid molecule in the mono‐ionized state. In the semi‐maleate ion, there is an asymmetric intramolecular hydrogen bond between the carboxy OH group and an O atom of the other carboxylate group. There are no direct hydrogen‐bonded interactions among the semi‐maleate anions.
In the title salt, C(5)H(10)NO(2)(+).C(4)H(5)O(6)(-), proline exists as a cation and the tartaric acid as a semi-tartrate anion. The semi-tartrate ions form hydrogen-bonded strings along the c axis. These strings are interconnected through the proline molecules, forming a layered network parallel to the bc plane. The proline molecules, however, do not directly interact among themselves, except for a weak C-H.O hydrogen bond.
Key indicatorsSingle-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.035 wR factor = 0.106 Data-to-parameter ratio = 7.9For details of how these key indicators were automatically derived from the article, see
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