After many years of fusion research, the conditions needed for a D–T fusion reactor have been approached on the Tokamak Fusion Test Reactor (TFTR) [Fusion Technol. 21, 1324 (1992)]. For the first time the unique phenomena present in a D–T plasma are now being studied in a laboratory plasma. The first magnetic fusion experiments to study plasmas using nearly equal concentrations of deuterium and tritium have been carried out on TFTR. At present the maximum fusion power of 10.7 MW, using 39.5 MW of neutral-beam heating, in a supershot discharge and 6.7 MW in a high-βp discharge following a current rampdown. The fusion power density in a core of the plasma is ≊2.8 MW m−3, exceeding that expected in the International Thermonuclear Experimental Reactor (ITER) [Plasma Physics and Controlled Nuclear Fusion Research (International Atomic Energy Agency, Vienna, 1991), Vol. 3, p. 239] at 1500 MW total fusion power. The energy confinement time, τE, is observed to increase in D–T, relative to D plasmas, by 20% and the ni(0) Ti(0) τE product by 55%. The improvement in thermal confinement is caused primarily by a decrease in ion heat conductivity in both supershot and limiter-H-mode discharges. Extensive lithium pellet injection increased the confinement time to 0.27 s and enabled higher current operation in both supershot and high-βp discharges. Ion cyclotron range of frequencies (ICRF) heating of a D–T plasma, using the second harmonic of tritium, has been demonstrated. First measurements of the confined alpha particles have been performed and found to be in good agreement with TRANSP [Nucl. Fusion 34, 1247 (1994)] simulations. Initial measurements of the alpha ash profile have been compared with simulations using particle transport coefficients from He gas puffing experiments. The loss of alpha particles to a detector at the bottom of the vessel is well described by the first-orbit loss mechanism. No loss due to alpha-particle-driven instabilities has yet been observed. D–T experiments on TFTR will continue to explore the assumptions of the ITER design and to examine some of the physics issues associated with an advanced tokamak reactor.

The Tokamak Fusion Test Reactor ͑TFTR͒ ͑R. J. Hawryluk, to be published in Rev. Mod. Phys.͒ experiments on high-temperature plasmas, that culminated in the study of deuterium-tritium D-T plasmas containing significant populations of energetic alpha particles, spanned over two decades from conception to completion. During the design of TFTR, the key physics issues were magnetohydrodynamic ͑MHD͒ equilibrium and stability, plasma energy transport, impurity effects, and plasma reactivity. Energetic particle physics was given less attention during this phase because, in part, of the necessity to address the issues that would create the conditions for the study of energetic particles and also the lack of diagnostics to study the energetic particles in detail. The worldwide tokamak program including the contributions from TFTR made substantial progress during the past two decades in addressing the fundamental issues affecting the performance of high-temperature plasmas and the behavior of energetic particles. The progress has been the result of the construction of new facilities, which enabled the production of high-temperature well-confined plasmas, development of sophisticated diagnostic techniques to study both the background plasma and the resulting energetic fusion products, and computational techniques to both interpret the experimental results and to predict the outcome of experiments.

We propose a reversible hydrogen storage mechanism for cycled sodium alanate. The individual mechanistic reaction steps for the decomposition reaction derive a set of time-dependent differential equations that simultaneously produce the evolution plots for each species. These plots reproduce several aspects of in situ X-ray diffraction (XRD) data, as well as the measured relative composition of selected decomposition samples at various extents of reaction. The presence of alanes facilitates both the decomposition and reformation of sodium alanate based on the principle of microscopic reversibility. A major role for the titanium dopant in catalyzed sodium alanate dynamics may be alloy formation at or near the surface of bulk aluminum that facilitates the formation and sorption properties of alanes. Published by Elsevier B.V.

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